1.
Dalton Trans
; 52(24): 8442-8448, 2023 Jun 20.
Article
in English
| MEDLINE
| ID: mdl-37272264
ABSTRACT
Many Cu catalyzed ATRC reactions suffer from low catalyst activity and stability. We have synthesized five 1,10-phenanthroline ligands substituted in the 5-position with α-aminophosphonate groups, through which the corresponding Cu complexes can be immobilized on Al2O3. These catalysts show similar activity and higher selectivity than the homogenous catalysts while being recyclable.