Assessment of workplace safety climate among power sector employees: A comparative study of cross-culture employer in Pakistan.

Pakistan's power sector has undergone extensive reforms to improve its technical and monetary performance over the last two decades. However, despite its fast-growing and hazardous nature, safety research remains limited in this context. This study aims to address this gap by assessing the level of safety climate in the power sector and comparing the safety climate in plants operated by multinational companies (MNCs) and local companies (LCs).To this end, five power plants operating in the southern part of the Punjab region (in Pakistan) were included in this study. The Nordic Occupational Safety Climate Questionnaire (NOSACQ-50), an analytical tool comprising of 50 items across seven dimensions, was used to determine the level of safety climate. An independent T-Test was then applied to compare the means in two different setups to draw a conclusion about overall safety climate differences. In MNCs, overall management/leadership perception improved; however, workers in both setups responded similarly in many cases. The lowest observed score in both setups was related to worker's prioritization of safety and risk non-acceptance. The study highlights the importance of a company's policies, procedures, and leadership commitments in creating a stronger safety climate by instilling trust in workers. The study further demonstrates that cross-cultural and strong policies devised by multinational companies help to improve the overall safety climate andconcludes that promoting an efficient and positive safety climate in the power sector is a long journey and that can only be achieved if all workers and leaders take on an active role.

Temporal variation in leachate composition of a newly constructed landfill site in Lahore in context to environmental pollution and risks.

This study investigated the seasonal and temporal variations in the extent and source of physiochemical and toxic trace elements in the Lakhodair landfill site of Lahore, Pakistan. For this purpose, systematic composite samples were collected every month, consecutively for 1 year, and analyzed for different physiochemical parameters and trace elements. The results of TDS, TSS, COD, NH3-N, BOD5, sulfate, sulfides, phenolic compounds, and oil and grease were higher than the national environmental quality standard (NEQs). The concentrations of trace elements, especially Mn (1.7 mg/L) and Cd (0.05 mg/L), were above the MPL, while Fe (14 mg/L), Ni (1.6 mg/L), and Zn (6.7 mg/L) were also found higher than the NEQs in some samples. In Lakhodair leachates, the TDS, COD, NH3-N, BOD5, sulfides, and Cl- have high concentration coefficient (i.e., CC 3 to > 6), which falls in the category of considerable to high contamination and risk level, while the remaining parameters were in the category of low to moderate contamination (CC 1 to ≤ 3) and moderate risk. The lower BOD5/COD ratio (< 0.1) in spring and autumn seasons represents the active methanogenesis and anaerobic activities in the Lakhodair landfill site. The anaerobic and methanogenesis activities enhance the redox reaction as a result of CO2 emission, which increases the pH, TDS, COD, Cl-, BOD5, NH3-N, sulfides, and phenolic compounds in the leachate site. However, the lower concentrations of some trace elements in leachate may be because of an anaerobic process that may immobilize the trace elements. It is presumed that the trace elements in the Lakhodair landfill may be in a metastable state, which is difficult to leach out. It is hereby recommended that leachate produced in the Lakhodair landfill site should be handled carefully to limit the environmental and health implications.

Effective Removal of Cr(VI) from Wastewater Using Biochar Derived from Walnut Shell.

Heavy metals are the major concern of the modern age. Among the heavy metals, chromium (Cr(VI)) is regarded as a highly toxic heavy metal released largely from leather tanning operations. To remove such high concentrations of Cr(VI), an advanced method is required urgently. Thus, biosorption using biochar, which is an organic material produced from various sources such as walnut shell, can be applied successfully for Cr(VI) abatement. The major objectives of this experiment were the remediation of the Cr(VI) heavy metal using walnut shell biochar and checking of the effect of pH, biochar dosage, Cr level, and shaking time. Remediation of Cr(VI) using walnut shell biochar was proved to be effective and removed the maximum concentration of Cr(VI) up to 93% at pH 5.5, 2 h agitation time, and the biochar amount of 1.1 g L-1 from an aqueous solution. Equilibrium modeling demonstrated that the chemisorption process was involved in adsorption of Cr(VI). The surface of the biochar was porous and provided numerous sites for Cr(VI) attachment, which was also confirmed by the presence of Cr(VI) onto the biochar after adsorption. Hence, the use of walnut shell biochar was highly effective as a sorbent, which could conveniently be applied to small-scale as well as large-scale levels.

Assessment of organochlorine pesticides and health risk in tobacco farming associated with River Barandu of Pakistan.

Diffuse pesticide pollution through tobacco fields is a serious threat to both natural integrities and living beings because tobacco is known as a pesticide-intensive crop. Upsurge in the knowledge of detrimental impacts caused by organochlorine pesticides (OCPs) has made them a burning issue particularly in developing countries. Pakistan is a country famous for its agro-based economy and simultaneously is the second most significant pesticide consumer in South Asian countries. The studied area is tobacco hub of the country. Thus, the present work is aimed to investigate the contamination profile that highlights the ecological and health risk posed by OCPs in River Barandu, located in the proximity of tobacco farming region. ΣOCP levels in sediments ranged between 32.918 and 98.810 ng/g and in water between 0.340 and 0.935 µg/L. Hexachlorocyclohexanes (HCHs) and heptachlor were the most prevailing pesticides in both matrices of the river. Isomeric composition of DDTs and HCHs highlighted that the ß-HCH and p,p'-DDT were dominant isomers in water, while α-HCH and p,p'-DDT in sediment compartment. Enantiomeric compositions of HCH and DDT indicate both recent and historic uses of these compounds in the area. Indirect contamination through nearby tobacco clusters has been depicted through spatial analysis. Ecological risk assessment based upon the risk quotient (RQ) method revealed that α-endosulfan, dieldrin, heptachlor, and ∑HCHs represent a very high level of ecological risks. The OCPs' lifetime carcinogenic and non-carcinogenic health risks associated with dermal exposure to river's water were considered nominal for surrounding populations. However, detailed ecological and health risk studies are recommended considering the bio-accumulating nature of these contaminants in the food chain.