Sustainable reclamation of synthetic materials as automotive parts replacement: effects of environmental response on natural fiber vulnerabilities.

Sustaining the resilience of the environment against climate change volatilities is fast becoming a herculean task considering the vulnerabilities of the ecosystem and disruption of the global value chain. Environmental crisis emanating from improper containment of synthetic materials is a major impediment facing the world today, and the situation could get worse if urgent measures are not devised to mitigate the quantity of waste synthetic materials that find its ways to the environment. These wastes are released in the form of toxins, posing danger to the environments, causing biodiversity loss and the degradation of already battered-climate. In this paper, the authors apprise existing containment measures of synthetic waste materials taking a preliminary and on-the-spot assessment of their impacts and effectiveness of their application leading to their operation. The prospect of waste glass fiber in automotive part replacement is given utmost interest in this paper, in which, a significant quantity of glass fiber could be used as part of automotive materials to reduce their overbearing environmental carnage. By this approach, the emerging automotive parts may have their strength and durability enhanced against impact and corrosion. Mindful of the non-biodegradable properties of glass fibers, the paper captures how effective these fibers could be used as automotive parts against the traditional materials. This paper also reflects on the response of the natural fiber in terms of their sustainability, as natural forest faces severe extinction occasioned by anthropogenic activities.

Mitigating environmental impact of waste glass materials: review of the existing reclamation options and future outlook.

The environmental impact of waste glass (WG) is one of the major challenges crippling sustainable waste management and mitigation. Reclamation of recycled materials from waste glass remains a tedious task amidst complex technological approaches. The challenge as seen in the global containment measures increase the proportion of waste glass and minimize the existing capacity of landfill space. In many works, findings have shown how best to minimize the impact of waste glass as evidenced in their inclusion as building materials such as cement, mortars, concretes and blocks. The concept of this paper is to appraise previous studies carried out on the use of waste glass as key contributing factor in structural building. The scope of this paper will be broaden to include various successes recorded in the evolution of concrete mixtures containing different proportion of recycle glass. Part of the setbacks noted in the inclusion of these recycled materials as matrix, filler or fibre are also reported in this paper. Also discussed is the durability of glass materials in varying conglomerate involving cement in reinforcement of building and structures. Thermal insulating properties of recycled glass are also considered in this work where considerable energy is saved due to their low thermal conductivity. Based on the analysis of various studies and other factors considered in this paper, it is established that recycled glass materials can be accommodated in structural buildings, while continuous research is necessary to adapt waste glass to high pH value of Portland cement.

A hybrid method for synthesis of integrated water and regeneration networks with variable removal ratios.

This work presents a systematic optimization framework that integrates graphical insights with mathematical modelling to reduce both model complexity and computational time. The graphical technique adopted in this work is Composite Table Algorithm (CTA), which is improved to determine an optimal regenerator removal ratio (RR) that simultaneously minimizes the freshwater requirement and wastewater generation within the water network. The improved CTA is demonstrated using literature examples for both fixed load and fixed flowrate problems. It is further adapted to solve a multiple contaminant problem using the reference contaminant approach. The mathematical model developed includes a detailed design of a reverse osmosis (RO) unit to allow for simultaneous optimization of water and energy used by the regenerator. This provides accurate cost estimation of the water network rather than the linear cost functions associated with the use of blackbox representations in graphical targeting. Upon integrating the graphical and mathematical techniques in this study, results show that there was a reduction of about 85% in CPU time. This implies that the model converges faster and therefore favours the use of insight-based techniques as a preprocessing step for mathematical modelling.

Cake Compressibility Analysis of BPOME from a Hybrid Adsorption-Microfiltration Process.

This study investigates the utility of a hybrid adsorption-membrane process for cake compressibility evaluation of biotreated palm oil mill effluent (BPOME). A low-cost empty fruit bunch (EFB) based powdered activated carbon (PAC) was employed for the upstream adsorption process with operation conditions of 60 g/L PAC dose, 68 min mixing time, and 200 rpm mixing speed to reduce the feed-water strength and alleviate probable fouling of the membranes. Two polyethersulfone microfiltration (MF) membranes of 0.1 and 0.2 µm pore sizes were investigated under constant transmembrane pressures (TMP) of 40, 80, and 120 kPa. The compressibility factors (z), which was obtained from the slopes of power plots (function of specific cake resistance (α) and pressure gradient) were evaluated. The z values of 0.32 and 0.52, respectively obtained, for the 0.1 and 0.2 µm MF membranes provided compressible and stable z values as observed from their power plots. Besides, these membranes were found suitable for the measurement of z since the results are in consonance with the established principle of cake compressibility. Moreover, the upstream adsorption mitigated the clogging of the membranes which ultimately led to moderate resistances and cake compressibility. These are indications that with the secondary cake filtration, a sustainable flux can be achieved during BPOME filtration. The membranes exhibited close to 100% restoration after cleaning.

Technical feasibility study of a low-cost hybrid PAC-UF system for wastewater reclamation and reuse: a focus on feedwater production for low-pressure boilers.

This study has applied the concept of the hybrid PAC-UF process in the treatment of the final effluent of the palm oil industry for reuse as feedwater for low-pressure boilers. In a bench-scale set-up, a low-cost empty fruit bunch-based powdered activated carbon (PAC) was employed for upstream adsorption of biotreated palm oil mill effluent (BPOME) with the process conditions: 60 g/L dose of PAC, 68 min of mixing time and 200 rpm of mixing speed, to reduce the feedwater strength, alleviate probable fouling of the membranes and thus improve the process flux (productivity). Three polyethersulfone ultrafiltration membranes of molecular weight cut-off (MWCO) of 1, 5 and 10 kDa were investigated in a cross-flow filtration mode, and under constant transmembrane pressures of 40, 80, and 120 kPa. The permeate qualities of the hybrid processes were evaluated, and it was found that the integrated process with the 1 kDa MWCO UF membrane yielded the best water quality that falls within the US EPA reuse standard for boiler-feed and cooling water. It was also observed that the permeate quality is fit for extended reuse as process water in the cement, petroleum and coal industries. In addition, the hybrid system's operation consumed 37.13 Wh m-3 of energy at the highest applied pressure of 120 kPa, which is far lesser than the typical energy requirement range (0.8-1.0 kWh m-3) for such wastewater reclamation.

A graphical technique for wastewater minimisation in batch processes.

Presented in this paper is a graphical technique for freshwater and wastewater minimisation in completely batch operations. Water minimisation is achieved through the exploitation of inter- and intra-process water reuse and recycle opportunities. In the context of this paper, a completely batch operation is one in which water reuse or recycle can only be effected either at the start or the end of the process. During the course of the operation, water reuse and recycle opportunities are completely nullified. The intrinsic two-dimensionally constrained nature of batch processes is taken into consideration. In the first instance, time dimension is taken as a primary constraint and concentration a secondary constraint. Subsequently, the priority of constraints is reversed so as to demonstrate the effect of the targeting procedure on the final design. Attention is brought to the fact that first and cyclic-state targeting are essential in completely batch operations. Moreover, the exploration and use of inherent storage in batch processes is demonstrated using a real-life case study. Like most graphical techniques, the presented methodology is limited to single contaminants.