Bromido(dodecafluorosubphthalo-cyaninato)boron(III).

The title compound, C(24)BBrF(12)N(6) or Br-F(12)BsubPc (BsubPc is boronsubphtalocyanine), has a bowl-shaped structure with an approximate mol-ecular C(3v) symmetry characteristic of boronsubphthalocyanine compounds. In the crystal, mol-ecules are arranged in one-dimensional columns and the boron-subphthalocyanine units within each column are offset and angled in a bowl-to-ligand packing arrangement such that the axial Br atom rests in the aromatic concaved bowl of the neighboring subphthalocyanine with an inter-molecular Br⋯B distance of 3.721 (3) Å.

(Dodecafluorosubphthalocyaninato)(4-methylphenolato)boron(III).

In the title compound, C(31)H(7)BF(12)N(6)O, mol-ecules are arranged into one-dimensional columns with an inter-molecular B⋯B distance of 5.3176 (8) Å. Bowl-shaped mol-ecules are arranged within the columns in a concave bowl-to-ligand arrangement separated by a ring centroid distance of 3.532 (2) Šbetween the benzene ring of the 4-methyl-phen-oxy ligand and one of the three five-membered rings of a symmetry-related mol-ecule.