1.
Chem Commun (Camb)
; 49(39): 4394-6, 2013 May 14.
Article
in English
| MEDLINE
| ID: mdl-23190945
ABSTRACT
Dinuclear cobalt-1,10-phenanthroline (1) and 2,2'-bipyridine (2) complexes bridged by 1,8-bis(2,2':6',2''-terpyrid-4'-yl)anthracene (btpyan) were prepared. Both of the complexes selectively catalysed the electrochemical four-electron reduction of dioxygen to H2O without the generation of H2O2 as a two-electron reduction product.