Insights in Pt-based electrocatalysts on carbon supports for electro-oxidation of carbohydrates: an EIS-DEMS analysis.

In this work, the electrochemical oxidation of carbohydrates (glucose, fructose, and sucrose) was induced at the interface of Pt-nanoparticles supported on different carbon-based materials as carbon vulcan (C) and carbon black (CB). It was found that the support plays an important role during carbohydrates electro-oxidation as demonstrated by electrochemical techniques. In this context, current-concentration profiles of the redox peaks show the behavior of the pathways at carbohydrates-based solutions. Herein, the trend of current measured was glucose > sucrose > fructose, attributed to differences in the organic functional groups and chain-structure. Raman, XRD, SEM-EDS and XPS put in clear important structural, morphological, and electronic differences linked with the intrinsic nature of the obtained material. Differential Electrochemical Mass Spectroscopy (DEMS) indicated that the selectivity and the conversion of the formed reaction products during oxidation is linked with the catalyst nature (distribution, particle size) and the interaction with the carbon-based support.

Characterization of functionalized multiwalled carbon nanotubes for use in an enzymatic sensor.

Carbon nanotubes (CNT) have proven to be materials with great potential for the construction of biosensors. Development of fast, simple, and low cost biosensors to follow reactions in bioprocesses, or to detect food contaminants such as toxins, chemical compounds, and microorganisms, is presently an important research topic. This report includes microscopy and spectroscopy to characterize raw and chemically modified multiwall carbon nanotubes (MWCNTs) synthesized by chemical vapor deposition with the intention of using them as the active transducer in bioprocessing sensors. MWCNT were simultaneously purified and functionalized by an acid mixture involving HNO3-H2SO4 and amyloglucosidase attached onto the chemically modified MWCNT surface. A 49.0% decrease in its enzymatic activity was observed. Raw, purified, and enzyme-modified MWCNTs were analyzed by scanning and transmission electron microscopy and Raman and X-ray photoelectron spectroscopy. These studies confirmed purification and functionalization of the CNTs. Finally, cyclic voltammetry electrochemistry was used for electrical characterization of CNTs, which showed promising results that can be useful for construction of electrochemical biosensors applied to biological areas.