1.
Chem Commun (Camb)
; (19): 2045-7, 2006 May 21.
Article
in English
| MEDLINE
| ID: mdl-16767270
ABSTRACT
A number of cationic gold(I) complexes have been synthesized and found to be stabilized by the use of N-heterocyclic carbene ligands. These species are often employed as in situ-generated reactive intermediates in gold catalyzed organic transformations. An isolated, well-defined species was tested in gold-mediated carbene transfer reactions from ethyl diazoacetate.
Subject(s)
Gold/chemistry , Heterocyclic Compounds/chemical synthesis , Methane/analogs & derivatives , Catalysis , Diazonium Compounds/chemistry , Heterocyclic Compounds/chemistry , Hydrocarbons/chemical synthesis , Hydrocarbons/chemistry , Methane/chemical synthesis , Methane/chemistry , Models, Chemical , Molecular Structure
2.
Chem Commun (Camb)
; (17): 1848-9, 2002 Sep 07.
Article
in English
| MEDLINE
| ID: mdl-12271639
ABSTRACT
N,N, N',N'-Tetraethylethylenediamine undergoes simple or double intramolecular dealkylation reactions in the presence of the complexes [RuCl2(diene)]n (diene = cod, nbd) or trans-[RuCl2(diene)(morfoline)2 at 80 degrees C to afford chelating amine ligands which contains one or two N-H functionalities.
