ABSTRACT
We demonstrated the deposition of the architecture of graphene oxide on stainless steel substrate and its potential environmental application. The synthesis and characterization of graphene oxide were described. The controlled formation of graphene oxide coatings in the form of the homogenous structure on stainless steel is demonstrated by scanning electron microscopy (SEM). The structure, morphology and properties of the material were assessed by Fourier transform infrared (FTIR) spectroscopy, X-ray photoelectron spectroscopy (XPS), Raman spectroscopy, transmission electron microscopy (TEM) and atomic force microscopy (AFM). The morphology and stability of these structures are shown to be particularly related to the pre-treatment of stainless steel substrate before the electrophoretic deposition. This approach opens up a new route to the facile fabrication of advanced electrode coatings with potential use in environmental applications.
ABSTRACT
The combination of several methods (X-ray diffraction, X-ray photoelectron spectroscopy, energy dispersive X-ray analysis, infrared spectroscopy) was applied to study the changes that have occurred during the adsorption of Zn(II) and Mn(II) ions on a carbonized sunflower sample for understanding a mechanism of heavy metals adsorption. Sunflower biochar was obtained from the stem and inflorescences sunflower wastes through pyrolysis at 600 °C for 30 min. According to the infrared spectroscopy and Boehm titration data, this carbonized material has acidic and basic functional groups on its surface, but they do not participate in the metal ions adsorption. However, the synthesized carbon proved to be a sustainable high-effective adsorbent for zinc(II) and manganese(II) ions removal with adsorption capacity 138.3 mg g-1 of Zn2+ and 45.4 mg g-1 for Mn2+. Surface analysis of the carbonized material by energy dispersive X-ray analysis, X-ray diffraction, and X-ray photoelectron spectroscopy indicated the presence of soluble and insoluble inorganic salts, such as KCl, NaCl, NaHCO3, KHCO3, CaCO3, MgCO3. It was established, that during the adsorption process, soluble salts are washed away, and new insoluble ones are formed assisting by Zn(II) and Mn(II) ions. It has been revealed that the adsorptive removal of Zn2+ and Mn2+ is caused by the precipitation mechanism. The efficiency of removing Zn(II) and Mn(II) ions from water contaminated with battery waste by the same mechanism is shown.
