Effect of nano-TiO2 size and utilization ratio on the performance of photocatalytic concretes; self-cleaning, fresh, and hardened state properties.

In this study, photocatalysis technology was used to reduce water pollution. Decolorization of Reactive Black 5 using nano-TiO2 (NT) as a photocatalyst was investigated by adsorption and degradation experiments. Effects of NT particle size and utilization ratio on the time-dependent flow performance, compressive-flexural strength, and Bohme abrasion resistance of cementitious systems were investigated. In addition to the NT-free control mixture, a total of six photocatalytic self-cleaning mortar mixtures (PSCM) were prepared using NT in two different particle sizes (28 and 38 nm) and three different ratios (0.5%, 1%, and 1.5%). The PSCM sample containing 38 nm NT exhibited superior performance in terms of photocatalytic properties compared to the 28 nm state. It was observed that the flow performance of PSCM mixtures with NT substitution is adversely affected regardless of the NT type. Mixtures containing NT with a lower particle size (28 nm) had higher compressive and flexural strengths.

Effect of Silica Fume Utilization on Structural Build-Up, Mechanical and Dimensional Stability Performance of Fiber-Reinforced 3D Printable Concrete.

It is known that 3D printable concrete mixtures can be costly because they contain high dosages of binder and that the drying-shrinkage performance may be adversely affected. Mineral additives and fibers are generally used to control these negative aspects. In this study, the use of silica fume, a natural viscosity modifying admixture, was investigated to improve the rheological and thixotropic behavior of 3D printable concrete mixtures reinforced with polypropylene fiber (FR-3DPC). The effect of increasing the silica fume utilization ratio in FR-3DPC on the compressive strength (CS), flexural strength (FS), and drying-shrinkage (DS) performance of the mixtures was also examined. A total of five FR-3DPC mixtures were produced using silica fume at the rate of 3, 6, 9, and 12% of the cement weight, in addition to the control mixture without silica fume. As a result of the tests, the dynamic yield stress value decreased with the addition of 3% silica fume to the control mixture. However, it was found that the dynamic yield stress and apparent viscosity values of the mixtures increased with the addition of 6, 9, and 12% silica fume. With the increase in the use of silica fume, the CS values of the mixtures were generally affected positively, while the FS and DS behavior were affected negatively.

Use of recycled mortar as fine aggregates in pavement concrete applications.

The use of recycled aggregates derived from construction and demolition wastes increased in the concrete construction industry. While the coarse fraction (i.e., from 5 to 20 mm) was successfully recycled, the fine fraction (i.e., from 0 to 5 mm) is hardly recyclable given its heterogenous nature and poor physical properties. This paper assesses the feasibility of recycled mortar aggregate (RMA) in pavement concrete applications requiring superior resistance to weathering and wearing effects. Three concrete strength grade categories prepared with different water-to-binder ratios (w/b) of 0.4, 0.5, and 0.6 are investigated; the natural sand replacement levels by RMA varied from 0 % to 60 % by volume, at 20 % increment rates. Test results showed that the detrimental RMA effect on durability depends on the concrete strength category, requiring proper adjustment of the maximum replacement rate to maintain acceptable losses in performance. Hence, the higher strength grade mixtures prepared with 0.4 w/b were found to yield significant drops in durability reaching 25 % in water sorptivity, 18 % in abrasion, and 22 % due to freeze/thaw (F/T) cycles. In contrast, the lower strength grade concrete made with 0.6 w/b exhibited marginal degradation in strength and durability, despite the incorporation of 60 % RMA. The resulting losses in sorptivity, abrasion, and F/T cycles were limited to 13 %, 8 %, and 12 %, respectively.

Clinical Success Rate of Compomer and Amalgam Class II Restorations in First Primary Molars: A Two-year Study.

Background and aims. The majority of failures in Class II amalgam restorations occur in the first primary molar teeth; in addition, use of compomer instead of amalgam for primary molar teeth restorations is a matter of concern. The aim ofthe present study was to compare the success rate of Class II compomer and amalgam restorations in the first primary molars. Materials and methods. A total of 17 amalgams and 17 compomer restorations were placed in 17 children based on a split-mouth design. Restorations were assessed at 12- and 24-month intervals for marginal integrity, the anatomic form and recurrent caries. Data were analyzed with SPSS 11. Chi-squared test was applied for the analysis. Statistical significance was set at P<0.05. Results. A total 34 restorations of 28 restorations (14 pairs) of the total restorations still survived after 24 months. Compomerrestorations showed significantly better results in marginal integrity. Recurrent caries was significantly lower incompomer restorations compared to amalgam restorations. Cumulative success rate at 24-month interval was significantlyhigher in compomer restorations compared to amalgam restorations. There was no statistically significant difference inanatomic form between the two materials. Conclusion. Compomer appears to be a suitable alternative to amalgam for Class II restorations in the first primary mo-lars.