An Atomistic Picture of Boron Oxide Catalysts for Oxidative Dehydrogenation Revealed by Ultrahigh Field 11B-17O Solid-State NMR Spectroscopy.

Boron oxide/hydroxide supported on oxidized activated carbon (B/OAC) was shown to be an inexpensive catalyst for the oxidative dehydrogenation (ODH) of propane that offers activity and selectivity comparable to boron nitride. Here, we obtain an atomistic picture of the boron oxide/hydroxide layer in B/OAC by using 35.2 T 11B and 17O solid-state NMR experiments. NMR spectra measured at 35.2 T resolve the boron and oxygen sites due to narrowing of the central-transition powder patterns. A 35.2 T 2D 11B{17O} dipolar heteronuclear correlation NMR spectrum revealed the structural connectivity between boron and oxygen atoms. The approach outlined here should be generally applicable to determine atomistic structures of heterogeneous catalysts containing quadrupolar nuclei.

The Use of Heterogeneous Catalysis in the Chemical Valorization of Plastic Waste.

Plastic solid waste (PSW) is an ever-growing environmental challenge for our society, as it not only ends up in landfills but also in waterways and oceans and is consequently entering the food chain. A key strategy to overcome this problem while also preserving carbon resources is to use PSW as a feedstock, evolving towards a circular economy. To implement this, mechanical as well as chemical recycling technologies must be developed. Indeed, owing to the high volume of PSW generated each year, mechanical recycling alone is not adequate for addressing this global challenge. Because of this, chemical recycling via thermal and heterogeneous catalytic conversion has received growing attention. This process has the potential to take PSW and convert it into usable monomers, fuels, synthesis gas, and adsorbents under more sustainable conditions than thermal degradation. This Review highlights the recent research advances in catalytic technologies for PSW conversion and valorization.