Ceramic Scaffolds for Bone Augmentation: Design and Characterization with SEM and Confocal Microscopy.

Bone scaffolds must fulfil numerous and sometimes contradictory characteristics: biocompatibility, bioactivity, high porosity, and appropriate mechanical strength. To tackle some of these issues, this study has several aims for the development of such scaffolds for dentistry applications: (i) to utilize appropriate materials (ceramics and sponges) and to introduce a novel, potentially performant ceramic material; (ii) to characterize the obtained scaffolds by using a range of methods; (iii) to compare and to correlate the assessment results with the scope to validate them reciprocally. There are two commercially available dental ceramics (i.e., Ceramco iC Natural Enamel (E) and Ceramco iC Natural Dentine (D), (DeguDent GmbH, Hanau-Wolfgang, Deutschland)) that are considered, as well as a new-developed porcelain (ceramic C). To obtain porous structures of scaffolds, each ceramic is introduced in two different sponges: a denser one, green (G) and a less dense one, blue (B). A total of 60 samples are manufactured and divided in six study groups, obtained by combining the above materials: GE, BE, GD, BD, GC, and BC (where the first letter represents the sponge type and the second one the utilized ceramic). Several methods are applied to characterize their chemical composition, as well as their macro- and micro-porosity: X-ray Diffraction (XRD), apparent porosity measurements, scanning electronic microscopy (SEM), and confocal microscopy (CM). The latter two methods image the inner (porous) and the outer/cortical (denser) areas of the samples. The results show a good porosity (i.e., dimensions and uniformity of pores) of around 65% for the final group BC, with satisfactory values of around 51% for BD and GC. A certain correlation is made between SEM, CM, and the apparent porosity results. The biocompatibility of the new ceramic C is demonstrated. Finally, a necessary trade-off is made with the mechanical strength of the obtained scaffolds, which was also evaluated. From this point of view, Group BD has the highest compressive strength of around 4 MPa, while Group BC comes second, with around 2 MPa. This trade-off between porosity and mechanical strength suggests a choice between Groups BC and BD, which are the best with regard to the porosity and mechanical strength criterium, respectively.

Assessment of Strains Produced by Thermal Expansion in Printed Circuit Boards.

The paper proposed an alternative optical metrology to classical methods (strain gauge measurements and numerical simulation) for strain determination on printed circuit board (PCBs) due to thermal loads. The digital image correlation (DIC) technique was employed to record the strain distribution in some particular areas of the PCB. A thermal load was applied using a heating chamber, and the measurements were performed at four different temperature steps (25 °C, 50 °C, 85 °C and 120 °C). An increase in the principal strains with temperature was observed. For validation, the principal strains on the PCB obtained with DIC were compared with the values from gauge strain measurements and numerical simulation. The conclusions highlighted that DIC represents a technique with potential for strain measurement caused by thermal deformation, with the advantages of full field measurement, less preparation of the surface and good accuracy.

Influence of the Printing Angle and Load Direction on Flexure Strength in 3D Printed Materials for Provisional Dental Restorations.

The CAD/CAM techniques, especially additive manufacturing such as 3D printing, constitute an ever-growing part of obtaining different dental appliances and restorations. Of these, provisional restorations are of frequent use in daily dental practice and are the object of this study. Masticatory and parafunctional forces determine flexure on these prostheses. This study investigates the influence of the printing angle and loading direction of the applied force on the flexure strength of two commercially available printable resins-Detax Freeprint Temp and Nextdent MFH Vertex dental. Ten rectangular beam specimens printed at the angle of 0, 45 and 90 degrees were fabricated of each of these materials, with an addition of 10 at 0 degrees for the investigation of the load direction. Three-point bending tests were performed in a universal testing machine. Flexure strength, strain at break and Young's modulus were determined and a statistical analysis was performed on the obtained data. According to the statistical analysis, the flexural strength has a significance dependence with respect to degrees of orientation, for both investigated materials.

Is Fracture Toughness of PUR Foams a Material Property? A Statistical Approach.

The published data on the experimentally determined fracture toughness of foams are based on a small number of specimens, having a lack of statistical consistency. The paper proposes a statistical approach on the fracture toughness results of rigid polyurethane (PUR) foams of three different densities. Five types of fracture tests were considered. The results were statistically analyzed using six types of regressions and a meta-analysis to identify the factors influencing the fracture toughness. The statistical analysis indicates that the fracture toughness represents a material property because does not depend on the specimen type. The density plays a major role in the fracture toughness of PUR foams. The irregular shape of the cells induced small anisotropy for low-density foams (100 kg/m3 and 145 kg/m3). This effect could not be observed for the foam with 300 kg/m3 density, for which the cells have a more regular spherical shape. The statistical analysis indicates that the influence of the loading speed is very weak.

Mode I Fracture Toughness of Polyamide and Alumide Samples obtained by Selective Laser Sintering Additive Process.

Selective Laser Sintering is a flexible additive manufacturing technology that can be used for the fabrication of high-resolution parts. Alongside the shape and dimension of the parts, the mechanical properties are essential for the majority of applications. Therefore, this paper investigates dimensional accuracy and mode I fracture toughness (KIC) of Single Edge Notch Bending samples under a Three Point Bending fixture, according to the ASTM D5045-14 standard. The work focuses on the influence of two major aspects of additive manufacturing: material type (Polyamide PA2200 and Alumide) and part orientation in the building environment (orientations of 0°, 45° and 90° are considered). The rest of the controllable parameters remains constant for all samples. The results reveal a direct link between the sample densities and the dimensional accuracy with orientation. The dimensional accuracy of the samples is also material dependent. For both materials, the angular orientation leads to significant anisotropic behavior in terms of KIC. Moreover, the type of material fundamentally influences the KIC values and the fracture mode. The obtained results can be used in the development of additive manufactured parts in order to obtain predictable dimensional tolerances and fracture properties.

Correlations between Process Parameters and Outcome Properties of Laser-Sintered Polyamide.

As additive manufacturing (AM) becomes more accessible, correlating process parameters with geometric and mechanical properties is an important topic. Because the number of process variables in AM is large, extensive studies must be conducted in order to underline every particular influence. The study focuses on two variables-part orientation in the orthogonal horizontal plane and energy density-and targets two outcomes-geometric and tensile properties of the parts. The AM process was conducted on selective laser sintering (SLS) machine EOS Formiga P100 using EOS white powder polyamide (PA2200). After finishing the sinterization process, the parts were postprocessed, measured, weighted, and mechanically tested. The geometric evaluation and mass measurements of every sample allowed us to compute the density of all parts according to the sinterization energy and orientation, and to determine the relative error of every dimension. By conducting the tensile testing, the elastic and strength properties were determined according to process variables. A linear trend regarding sample density and energy density was identified. Also, large relative dimensional errors were recorded for the lowest energy density. Mechanical properties encountered the highest value for the highest energy density at a 45° orientation angle.

Influence of Manufacturing Parameters on Mechanical Properties of Porous Materials by Selective Laser Sintering.

This paper presents a study on the tensile properties of Alumide and polyamide PA2200 standard samples produced by Additive manufacturing (AM) based on selective laser sintering (SLS). Because of the orthogonal trajectories of the laser beam during exposure, different orientations of the samples may lead to different mechanical properties. In order to reveal this process issue, four orientations of the samples in building envelope were investigated. For data reliability, all the other process parameters were constant for each material and every orientation. The tensile tests highlight small differences in elastic properties of the two materials, while significant differences in strength properties and energy absorption were observed. Nevertheless, Young modulus indicates high stiffness of the Alumide comparing to PA2200 samples. The stereo microscopy reveals a brittle fracture site for Alumide and a ductile fracture with longitudinal splitting zones for PA2200. From the orientation point of view, similar properties of samples oriented at 0 and 90 degrees for all investigated mechanical properties were observed. However, tensile strength was less influenced by the sample orientations.

Poisson's Ratio of Closed-Cell Aluminium Foams.

A nondestructive impulse excitation technique was used to investigate Poisson's ratio of powder metallurgical pure closed-cell aluminium foams according to ASTM E 1876 within the foam density range of 0.430⁻1.390 g·cm-3. Instead of a constant value of 0.34, as according to Gibson and Ashby's assumption for the Poisson's ratio of metallic foams, the decrease of the Poisson's ratio with decreasing foam density was observed. Observed Poisson's ratio data were in the range of 0.21⁻0.34. To check the validity of the results, the Young's modulus was calculated using Poisson's ratio and its dependence on relative density was successfully modelled using the usual power law function with characteristic exponent of 1.72 ± 0.1. This confirms that the obtained experimental results for Poisson's ratio are valid. Finally, rule of mixture and percolation theory were used to model the observed decrease of Poisson's ratio with increasing porosity.

On the Lateral Compressive Behavior of Empty and Ex-Situ Aluminum Foam-Filled Tubes at High Temperature.

In this research work, the effect of lateral loading (LL) on the crushing performance of empty tubes (ETs) and ex situ aluminum foam-filled tubes (FFTs) was investigated at 300 °C. The cylindrical thin-walled steel tube was filled with the closed-cell aluminum alloy foam that compressed under quasi-static loading conditions. During the compression test, the main mechanical properties of the ETs improved due to the interaction effect between the cellular structure of the foam and the inner wall of the empty tube. In addition, the initial propagated cracks on the steel tubes reduced considerably as a result of such interaction. Furthermore, the obtained results of the LL loading were compared with the axial loading (AL) results for both ETs and FFTs at the same temperature. The findings indicated that the application of loading on the lateral surface of the composite causes the lower mechanical properties of both ETs and FFTs in comparison with the axial loading conditions.