1.
Chem Commun (Camb)
; 60(13): 1794-1797, 2024 Feb 08.
Article
in English
| MEDLINE
| ID: mdl-38258886
ABSTRACT
Conjugated 1-bromo or 1-iodo-1,3-dienes bearing a sulfide substituent have been synthesized via 1,2-sulfur migration from propargylic thioethers upon activation with NIS or NBS. The reaction generally proceeds with high control over the regio- and diastereoselectivity. Highly substituted thiophenes and selenophenes are easily obtained from the generated dienes.