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Unprecedented eight-palladium(I) crown-cycle with metal-metal unsupported bonds.
Angurell, Inma; Martínez-Ruiz, Isabel; Rossell, Oriol; Seco, Miquel; Gómez-Sal, Pilar; Martin, Avelino.
Chem Commun (Camb) ; (15): 1712-3, 2004 Aug 07.
Article in English | MEDLINE | ID: mdl-15278150

ABSTRACT

Tri(N-pyrrolyl)phosphine reacted with the sigma/pi complex [Pd(mu-Cl)(COD-MeO)]2 to give the octa-cycle [Pd(mu-Cl)[P(pyrl)3]]8 containing four Pd(I)-Pd(I) unbridged bonds.

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