Microfluidic processing of concentrated surfactant mixtures: online SAXS, microscopy and rheology.

We investigate the effect of microfluidic flow on the microstructure and dynamics of a model surfactant mixture, combining synchrotron Small Angle X-ray Scattering (SAXS), microscopy and rheology. A system comprising a single-chain cationic surfactant, hexadecyl trimethyl ammonium chloride (C16TAC), a short-chain alcohol (1-pentanol) and water was selected for the study due to its flow responsiveness and industrial relevance. Model flow fields, including sequential contraction-expansion (extensional) and rotational flows, were investigated and the fluid response in terms of the lamellar d-spacing, orientation and birefringence was monitored in situ, as well as the recovery processes after cessation of flow. Extensional flows are found to result in considerable d-spacing increase (from approx 59 Å to 65 Å). However, under continuous flow, swelling decreases with increasing flow velocity, eventually approaching the equilibrium values at velocities ≃2 cm s(-1). Through individual constrictions we observe the alignment of lamellae along the flow velocity, accompanied by increasing birefringence, followed by an orientation flip whereby lamellae exit perpendicularly to the flow direction. The resulting microstructures are mapped quantitatively onto the flow field in 2D with 200 µm spatial resolution. Rotational flows alone do not result in appreciable changes in lamellar spacing and flow type and magnitude evidently impact the fluid microstructure under flow, as well as upon relaxation. The findings are correlated with rheological properties measured ex situ to provide a mechanistic understanding of the effect of flow imposed by tubular processing units in the phase behavior and performance of a model surfactant system with ubiquitous applications in personal care and coating industries.

Annihilation of an AB/BA interface pair in superfluid helium-3 as a simulation of cosmological brane interaction.

This study presents measurements of the transport of quasiparticle excitations in the B phase of superfluid 3He at temperatures below 0.2Tc. We find that creating and then removing a layer of A-phase superfluid leads to a measurable increase in the thermal impedance of the background B phase. This increase must be due to the survival of defects created as the AB and BA interfaces on either side of the A-phase layer annihilate. We speculate that a new type of defect may have been formed. The highly ordered A-B interface may be a good analogy for branes discussed in current cosmology. If so, these experiments may provide insight into how the annihilation of branes can lead to the formation of topological defects such as cosmic strings.