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Chem Commun (Camb) ; 51(4): 658-60, 2015 Jan 14.
Article in English | MEDLINE | ID: mdl-25415618

ABSTRACT

In the presence of a thiourea catalyst, ß-CF3 nitroalkenes react with Hantzsch esters in a highly enantioselective fashion, giving a broad range of ß-CF3 amine precursors with a tertiary stereocentre at the ß-position. This reaction represents the first general catalytic enantioselective approach to this important class of ß-CF3 amines.

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