1.
Chem Commun (Camb)
; 55(47): 6787-6790, 2019 Jun 06.
Article
in English
| MEDLINE
| ID: mdl-31120080
ABSTRACT
The formation of [2]rotaxanes via a fumaramide-templated clipping reaction using α,α'-dimethyl-p-xylylenediamines is described. This process selectively affords two out of seven possible interlocked isomers due to a noticeable effect of the methyl groups on the in/out disposition of the amide CO groups.
2.
Chem Commun (Camb)
; 51(77): 14501-4, 2015 Oct 04.
Article
in English
| MEDLINE
| ID: mdl-26280034
ABSTRACT
Novel mechanized silica nanoparticles incorporating a peptide-based molecular shuttle as a photo-responsive interlocked gatekeeper of nanocontainers are described including the uptake and delivery studies of a model cargo.