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1.
Bioprocess Biosyst Eng ; 47(2): 235-247, 2024 Feb.
Article in English | MEDLINE | ID: mdl-38170236

ABSTRACT

This paper presents the analysis of a pilot anaerobic digestion plant that operates with organic fraction of municipal solid waste (OFMSW) from a wholesale market and can treat up to 500 kg d-1. The process was monitored for a period of 524 days during which the residue was characterized and the biogas production and methane content were recorded. The organic load rate (OLR) of volatile solids (VS) was 0.89 kg m-3 d-1 and the Hydraulic Retention Time (HRT) was 25 d during the process. The yield was 82 Nm3 tons OFMSW-1 biogas, equivalent to 586 Nm3 tons CH4 VS-1. The results obtained in the pilot plant were used to carry out a technical-economic evaluation of a plant that treats 50 tons of OFMSW from wholesale markets. A production of 3769 Nm3 d-1 of biogas and 2080 Nm3 d-1 of methane is estimated, generating 35.1 MWh d-1 when converted to electricity.


Subject(s)
Refuse Disposal , Solid Waste , Solid Waste/analysis , Refuse Disposal/methods , Anaerobiosis , Biofuels , Bioreactors , Methane
2.
Environ Sci Technol ; 51(15): 8643-8653, 2017 Aug 01.
Article in English | MEDLINE | ID: mdl-28686428

ABSTRACT

Society currently relies heavily on centralized production and large scale distribution infrastructures to meet growing demands for goods and services, which causes socioeconomic and environmental issues, particularly unsustainable resource supply. Considering local production systems as a more sustainable alternative, this paper presents an insight-based approach to the integrated design of local systems providing food, energy, and water to meet local demands. The approach offers a new hierarchical and iterative decision and analysis procedure incorporating design principles and ability to examine design decisions, in both synthesis of individual yet interconnected subsystems and integrated design of resource reuse across the entire system. The approach was applied to a case study on design of food-energy-water system for a locale in the U.K.; resulting in a design which significantly reduced resource consumption compared to importing goods from centralized production. The design process produced insights into the impact of one decision on other parts of the problem, either within or across different subsystems. The result was also compared to the mathematical programming approach for whole system optimization from previous work. It was demonstrated that the new approach could produce a comparable design while offering more valuable insights for decision makers.


Subject(s)
Conservation of Natural Resources , Water Supply , Conservation of Energy Resources , Water
3.
Bioresour Technol ; 243: 135-146, 2017 Nov.
Article in English | MEDLINE | ID: mdl-28651133

ABSTRACT

This paper presents material flow and sustainability analyses of novel mechanical biological chemical treatment system for complete valorization of municipal solid waste (MSW). It integrates material recovery facility (MRF); pulping, chemical conversion; effluent treatment plant (ETP), anaerobic digestion (AD); and combined heat and power (CHP) systems producing end products: recyclables (24.9% by mass of MSW), metals (2.7%), fibre (1.5%); levulinic acid (7.4%); recyclable water (14.7%), fertiliser (8.3%); and electricity (0.126MWh/t MSW), respectively. Refuse derived fuel (RDF) and non-recyclable other waste, char and biogas from MRF, chemical conversion and AD systems, respectively, are energy recovered in the CHP system. Levulinic acid gives profitability independent of subsidies; MSW priced at 50Euro/t gives a margin of 204Euro/t. Global warming potential savings are 2.4 and 1.3kg CO2 equivalent per kg of levulinic acid and fertiliser, and 0.17kg CO2 equivalent per MJ of grid electricity offset, respectively.


Subject(s)
Biofuels , Refuse Disposal , Solid Waste , Garbage , Metals
4.
Bioresour Technol ; 215: 131-143, 2016 Sep.
Article in English | MEDLINE | ID: mdl-27085988

ABSTRACT

This paper, for the first time, reports integrated conceptual MBCT/biorefinery systems for unlocking the value of organics in municipal solid waste (MSW) through the production of levulinic acid (LA by 5wt%) that increases the economic margin by 110-150%. After mechanical separation recovering recyclables, metals (iron, aluminium, copper) and refuse derived fuel (RDF), lignocelluloses from remaining MSW are extracted by supercritical-water for chemical valorisation, comprising hydrolysis in 2wt% dilute H2SO4 catalyst producing LA, furfural, formic acid (FA), via C5/C6 sugar extraction, in plug flow (210-230°C, 25bar, 12s) and continuous stirred tank (195-215°C, 14bar, 20min) reactors; char separation and LA extraction/purification by methyl isobutyl ketone solvent; acid/solvent and by-product recovery. The by-product and pulping effluents are anaerobically digested into biogas and fertiliser. Produced biogas (6.4MWh/t), RDF (5.4MWh/t), char (4.5MWh/t) are combusted, heat recovered into steam generation in boiler (efficiency: 80%); on-site heat/steam demand is met; balance of steam is expanded into electricity in steam turbines (efficiency: 35%).


Subject(s)
Levulinic Acids/chemical synthesis , Biofuels , Charcoal/chemistry , Garbage , Lignin/chemistry , Metals/chemistry , Recycling , Solid Waste , Sulfuric Acids/chemistry
5.
Environ Sci Technol ; 49(9): 5805-12, 2015 May 05.
Article in English | MEDLINE | ID: mdl-25855030

ABSTRACT

For sustainability's sake, the establishment of bioenergy production can no longer overlook the interactions between ecosystem and technological processes, to ensure the preservation of ecosystem functions that provide energy and other goods and services to the human being. In this paper, a bioenergy production system based on heathland biomass is investigated with the aim to explore how a system dynamics approach can help to analyze the impact of bioenergy production on ecosystem dynamics and services and vice versa. The effect of biomass harvesting on the heathland dynamics, ecosystem services such as biomass production and carbon capture, and its capacity to balance nitrogen inputs from atmospheric deposition and nitrogen recycling were analyzed. Harvesting was found to be beneficial for the maintenance of the heathland ecosystem if the biomass cut fraction is higher than 0.2 but lower than 0.6, but this will depend on the specific conditions of nitrogen deposition and nitrogen recycling. With 95% recycling of nitrogen, biomass production was increased by up to 25% for a cut fraction of 0.4, but at the expense of higher nitrogen accumulation and the system being less capable to withstand high atmospheric nitrogen deposition.


Subject(s)
Biofuels , Biotechnology/methods , Ecosystem , Atmosphere/chemistry , Biomass , Carbon/analysis , Nitrogen/analysis , Soil/chemistry , United Kingdom
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