ABSTRACT
Three-dimensional spiral waves in the Belousov-Zhabotinsky reaction are pinned to unexcitable heterogeneities. This pinning can prevent the collapse of scroll rings even if the heterogeneity does not extend along the entire wave filament. In the latter case, frequency differences create stationary gradients in the rotation phase. These twist patterns and their frequencies agree with algebraic solutions of the forced Burgers equation revealing insights into the phase coupling of scroll waves.
ABSTRACT
We report a transition from traveling to standing domain walls in a parametrically forced two-dimensional oscillatory Belousov-Zhabotinsky chemical reaction in 4:1 resonance. Our experimental results demonstrate spatiotemporal solutions not predicted by previous analytic results of the complex Ginzburg-Landau amplitude equation and numerical results from reaction-diffusion models. In addition to the stationary pi fronts at high forcing amplitudes, the 4:1 resonant patterns we observe include stationary pi/2 fronts.
ABSTRACT
Using an open-flow reactor periodically perturbed with light, we observe subharmonic frequency locking of the oscillatory Belousov-Zhabotinsky chemical reaction at one-sixth the forcing frequency (6:1) over a region of the parameter space of forcing intensity and forcing frequency where the Farey sequence dictates we should observe one-third the forcing frequency (3:1). In this parameter region, the spatial pattern also changes from slowly moving traveling waves to standing waves with a smaller wavelength. Numerical simulations of the FitzHugh-Nagumo equations show qualitative agreement with the experimental observations and indicate that the oscillations in the experiment are a result of period doubling.
ABSTRACT
Uniform oscillations in spatially extended systems resonate with temporal periodic forcing within the Arnold tongues of single forced oscillators. The Arnold tongues are wedge-like domains in the parameter space spanned by the forcing amplitude and frequency, within which the oscillator's frequency is locked to a fraction of the forcing frequency. Spatial patterning can modify these domains. We describe here two pattern formation mechanisms affecting frequency locking at half the forcing frequency. The mechanisms are associated with phase-front instabilities and a Turing-like instability of the rest state. Our studies combine experiments on the ruthenium catalyzed light-sensitive Belousov-Zhabotinsky reaction forced by periodic illumination, and numerical and analytical studies of two model systems, the FitzHugh-Nagumo model and the complex Ginzburg-Landau equation, with additional terms describing periodic forcing.
Subject(s)
Oscillometry/methods , Biomechanical Phenomena , Biophysics/methods , Electrochemistry/methods , Gels , Light , Models, Chemical , Models, Statistical , Models, Theoretical , Nonlinear Dynamics , Time FactorsABSTRACT
We examine the effects of controlled, slowly varying spatial inhomogeneities on spiral wave dynamics in the light sensitive Belousov-Zhabotinsky chemical reaction-diffusion system. We measure the speed of the grain boundary that separates two spirals, the speed of the lower frequency spiral being swept away by the grain boundary, and the speed of the slow drift of the highest frequency spiral. The grain boundary speeds are shown to be related to the frequency of rotation and wave number of the spiral pattern, as predicted from analysis of the complex Ginzburg-Landau equation [M. Hendrey, Phys. Rev. Lett.10.1103/PhysRevLett.82.859 82, 859 (1999); M. Hendrey,, Phys. Rev. E10.1103/PhysRevE.61.4943 61, 4943 (2000)].
ABSTRACT
We observe breathing front dynamics which select three distinct types of bistable patterns in the 2:1 resonance regime of the periodically forced oscillatory Belousov-Zhabotinsky reaction. We measure the curvature-driven shrinking of a circular domain R approximately t(1/2) at forcing frequencies below a specific value, and show that the fast time scale front oscillations (breathing) drive this slow time scale shrinking. Above a specific frequency, we observe fronts of higher curvature grow instead of shrink and labyrinth patterns form. Just below the transition frequency is a relatively narrow range of frequencies where the curvature-driven coarsening is balanced by a competing front interaction, which leads to a pattern of localized structures. The length scale of the localized structure and labyrinth patterns is set by the front interactions.
ABSTRACT
Experiments on a periodically forced Belousov-Zhabotinsky chemical reaction show front breakup into a state of spatiotemporal disorder involving continual events of spiral-vortex nucleation and destruction. Using the amplitude equation for forced oscillatory systems and the normal form equations for a curved front line, we identify the mechanism of front breakup and explain the experimental observations.
