ABSTRACT
In this work, the influence of simple acids in the room temperature sol-gel synthesis of TiO2 was investigated and the efficiency of prepared photocatalysts was evaluated in the removal of caffeine. To improve the photoactivity of TiO2, vanadium-doped TiO2 (VTiO2) samples were obtained starting from different amount of vanadyl sulphate as a dopant source. The samples were centrifuged, washed and finally dried at room temperature, and no calcination step was carried out. The prepared photocatalysts were characterized by different techniques (X-ray powder diffraction (XRD), specific surface area (SSA), ultraviolet-visible diffuse reflectance spectra (UV-vis DRS) and Raman). VTiO2 photocatalysts were tested in the photocatalytic removal of aqueous solutions containing caffeine. The photocatalytic tests were carried out in a recirculating batch cylindrical photoreactor irradiated by a UV LEDs strip (nominal power of 12 W and wavelength emission peak at about 365 nm) surrounding the external surface of the reactor. The optimized VTiO2 photocatalyst was able to reach a caffeine degradation of about 96% after 360 min of UV light irradiation with a total organic carbon (TOC) removal of 72%.
ABSTRACT
A continuous flow micro-reactor irradiated by UV-LEDs was employed to treat coloured wastewater by adsorption and simultaneous photocatalysis. Zinc oxide (ZnO) immobilized on commercial zeolites pellets in spherical shape (ZEO) was used as catalytic material in a micro-reactor maximizing the photocatalyst exposition to light sources, irradiating uniformly the entire solution volume and improving the mass transfer phenomena. Experimental tests were carried out on crystal violet dye (CV) as one of the main dying agent present in textile wastewater. The comparison between adsorption and adsorption/photocatalytic tests showed that UV irradiation can achieve a steady state CV concentration value corresponding to an equilibrium condition between adsorption and photocatalytic oxidation. The higher removal efficiency (i.e. 93%) was observed with a liquid flow rate of 1.1â¯mL/min (contact timeâ¯=â¯4.7â¯min; CVâ¯=â¯10â¯mg/L) under UV light irradiation. In the steady state, CV removal remained constant for the overall testing time. Bioassays evidenced that toxicity was not completely removed (i.e. final effluent ranked as "slight acute toxic") from wastewater suggesting its suitability for sewage collection discharge. A Dubinin Radushkevich (D-R) isotherm model was applied for studying the adsorption behaviour of ZnO/ZEO sample. CV adsorption constants were evaluated from experimental data carried out in dark conditions in a batch system. Kinetic expression of CV removal and the D-R adsorption were incorporated in the CV mass balance estimating the kinetic parameter. The model was validated comparing the calculated CV conversion with the experimental tests collected at different CV inlet concentration.
