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Phytochemistry ; 61(6): 669-73, 2002 Nov.
Article in English | MEDLINE | ID: mdl-12423887

ABSTRACT

Biotransformation of 3,6-dialkylcyclohexane-1,2-diones by cell suspension cultures of Marchantia polymorpha involves regioselective oxidative cleavage of the C-C bond to give the corresponding oxocarboxylic acids shortened by one carbon unit. In the case of cyclohexane-1,2-dione, adipic acid was obtained.


Subject(s)
Cyclohexanes/metabolism , Hepatophyta/metabolism , Cells, Cultured , Cyclohexanes/chemistry , Hepatophyta/cytology , Magnetic Resonance Spectroscopy , Oxidation-Reduction , Spectrometry, Mass, Electrospray Ionization , Spectroscopy, Fourier Transform Infrared
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