ABSTRACT
Harmattan dust and traffic-related pollution have been a serious environmental concern in the West African sub-region. In order to further contribute to the understanding of ambient levels of atmospheric pollution and chemical composition in the region, this study monitored harmattan dust and traffic-related particulate matter at four locations across southwestern (Ile-Ife) and north-western (Zaria) geo-political zones of Nigeria. The collected samples were characterized for their chemical composition using Energy-Dispersive X-Ray Fluorescence spectrometer equipped with an optimized secondary target x-ray excitation conditions (Al, CaF2, Fe, Ge, Zr, Mo, Ag, Al2O3). The objectives are to assess spatio-temporal mass concentrations, chemical footprints, enrichment factors, elemental correlations, and ratios at all locations. The X-ray analytical method was validated with a NIST SRM 2783 air particulate standard, and detection limits for each chemical specie were determined. Validation results showed good reproducibility of the certified reference material with relative standard deviations of the elements much lower by about 1-13% than the corresponding reference values. Mass concentrations reached up to 2200 µgm-3 in the north and 1500 µgm-3 in the south. The range of mean concentration of crustal marker elements were Al (5-27 µgm-3), Si (5-856 µgm-3), Ca (0.78-13 µgm-3), and Fe (2-13 µgm-3), and were most abundant during the harmattan particularly in the southwestern region. Highest mean concentration values of 380, 810, and 420 ngm-3 were recorded for Cr, Cu, and Pb respectively at the traffic corridor which also recorded the highest enrichment factors. Black carbon and elemental concentrations contributed between 1 to 54% and 9 to 94% across the locations respectively. Backward trajectories of atmospheric flow over the locations showed two dominant sources; dust laden source from the Sahara desert and maritime flow over the Gulf of Guinea. This study found that chemical footprints (Al, Si, K, Ca, Ti, and Fe) of harmattan-related dust were more correlated (r2 between 0.88 and 0.99) than those attributed to dust re-suspension at the traffic location.
Subject(s)
Air Pollutants/analysis , Dust/analysis , Africa, Northern , Environmental Monitoring , Nigeria , Particulate Matter/analysis , Reproducibility of ResultsABSTRACT
This study investigated impacts of climate variability on mosquito survival at Obafemi Awolowo University Campus, Ile-Ife, south-western Nigeria, and determined the regional climate suitability level for malaria transmission between 1996 and 2015. It employed some established climate-dependent models to simulate daily mosquito survival probabilities, p and a fuzzy logic suitability (FLS) model to determine the suitability conditions for malaria transmission across seasons. Multivariate regression analysis and lag correlation up to 4 months were performed to examine contributions of climate variation to the reported malaria cases. Results revealed that mosquitoes could survive all-year round with p values ranging between 0.40 and 0.96 under the prevailing mean climate. However, the climate suitability level for transmission of malaria was 'moderate' (0.45 < p ≤ 0.60) in the dry season but 'very high' (0.75 < p ≤ 0.96) in the wet. Rainfall was found to be the best predictor (r = 0.7, R2 = 0.448, p < 0.05) and no significant time-delay effect was noticed between climatic variables and malaria occurrence except for wind speed at 1-month lag. About 61% (multiple R2= 0.613 at p = 0.1) of monthly variations in reported malaria cases were accounted for by climate variability. Further probe revealed that non-climatic factors such as behavioural and socio-cultural status of the students' population played a very important role in malaria transmission and occurrence. The findings suggested that effective malaria control and interventions must integrate the crucial roles of both climatic and non-climatic factors in the study area.
