Direct Homogeneous Synthesis of Compounds with Two O Atoms and Long-Chain Hydrocarbons from CO and H2: Co-Ru/N-methylpyrrolidone Catalyst.

The homogeneous acetic acid synthesis-type Ru-Co-Li/N-methylpyrrolidone catalyst for CO and H2 transformations has been studied at moderately high pressures. For 1CO:2H2, low acetic acid selectivity has been observed, along with remarkable methyl acetate selectivity, the absence of aldehydes and ethyl acetate and sharp deviations from the Anderson-Schultz-Flory distribution for both alcaohols and long-chain hydrocarbons. For 1CO:1H2 and slightly elevated pressure, acetic acid selectivity slightly increased, notable ethyl acetate formation was detected, and both long-chain hydrocarbons and alcohols disappeared. Hypotheses are discussed about the direct parallel formation of all observed product groups (hydrocarbons, alcohols, esters, and acetic acid) and hydrocarbon chain growth limitations according to the formed Ru-Co cluster size in the presence of the aforementioned catalytic system.

Cobalt-Containing Dispersion Catalysts for Three-Phase Fischer-Tropsch Synthesis.

Nanosized catalyst dispersions have significant potential for improving hydrocarbon production from carbon monoxide and hydrogen via Fischer-Tropsch synthesis, an essential alternative to the use of petroleum as a raw material. New dispersed cobalt catalysts and dispersed-phase cobalt-based catalysts with Pd, Al2O3, or ZrO2 additives for the Fischer-Tropsch synthesis were synthesized in the present work. A dispersed cobalt phase was prepared in a heavy paraffin medium using ex situ and in situ approaches through thermal decomposition of a nitrate precursor at various temperatures. Analyses showed that an increase in the temperature for catalytic suspension formation from 215 to 260°C enlarged the particles in the dispersed phase from 190 to 264 nm, which was probably due to increased agglomeration at elevated temperatures. The rheological properties of the obtained catalytic suspensions can be described by the Bingham equation. Furthermore, the concentration of the dispersed phase had a direct impact on the structure of the entire catalytic system. Ultrafine suspensions of palladium-promoted catalytic systems were tested for the Fischer-Tropsch synthesis. The overall yield of C5+ hydrocarbons was as high as 50 g/m3, and the productivity of the Pd-promoted catalytic systems reached 270-290 g/(kgCo · h).