ABSTRACT
In perovskite solar cells (PSCs), the charge carrier recombination obstacles mainly occur at the ETL/perovskite and HTL/perovskite interfaces, which play a decisive role in the solar cell performance. Therefore, this study aims to enhance the flexible PSC (FPSC) efficiency by adding the newly designed CBz-PAI-interlayer (simply CBz-PAI-IL) at the perovskite/HTL interface. In addition, substantial work has been carried out on five different HTLs (Se/Te-Cu2O, CuGaO2, V2O5, and CuSCN, including conventional Spiro-OMeTAD as a reference HTL with and without CBz-PAI-IL), using drift-diffusion simulation to find suitable FPSC design to attain the maximum PCE. Interestingly, PET/ITO/AZO/ZnO NWs/FACsPbBrI3/CBz-PAI/Se/Te-Cu2O/Au device architecture demonstrates the highest achievable power conversion efficiency (PCE) of 27.9 %. The findings of this study confirmed that the reference device (without IL) displays a large valence band edge (VBE)/highest occupied molecular orbital (HOMO) energy level misalignment compared to the modified interface device (with CBz-PAI-IL that reduces VBE/HOMO level mismatch) that eases the hole transport, simultaneously, it reduces the charge carrier recombinations at the interface, resulting in diminished Voc losses in the device. Furthermore, the influence of perovskite absorber thickness and defect density, parasitic resistances, and working temperature are systematically examined to govern the superior FPSC efficiency and concurrently understand the device physics.
ABSTRACT
Due to their excellent properties, Zinc oxide nanowires (ZnO NW) have been attractive and considered as a promising electron-transporting layer (ETL) in flexible Perovskite Solar Cells (FPSCs). Since the first report on ZnO NWs-based FPSCs giving 2.6 % power conversion efficiency (in 2013), great improvements have been made, allowing to reach up toâ¼15 % nowadays. However, some issues still need to be addressed, especially on flexible substrates, to achieve uniform and well-aligned ZnO NWs via low-cost chemical solution techniques. Several parameters, such as the growing method (time, temperature, precursors concentration), addition of seed layer (thickness, roughness, annealing temperature) and substrate (rigid or flexible), play a crucial role in ZnO NWs properties (i.e., length, diameter, density and aspect ratio). In this review, these parameters allowing to control the properties of ZnO NWs, like the growth techniques, utilization of seed layers and the growing method (time or precursors concentration) have been summarized. Then, a particular focus on the ZnO NW's role in FPSCs as well as the use of these results on the development of ZnO NWs-based FPSCs have been highlighted.
ABSTRACT
Double halide perovskites have received massive attention due to their low toxicity, tunable bandgap, structural flexibility, and stability as compared to conventional 3D lead halide perovskites. Particularly, newly discovered formamidinium germanium-antimony halide (FA4GeSbCl12) double perovskites offer an excellent bandgap (â¼1.3 eV) for solar cell (SC) applications. Therefore, in this study, for the first time, we have simulated FTO/TiO2/FA4GeSbCl12/Cu2O/Au planar SCs using SCAPS-1D, showing a maximum power conversion efficiency of 22.5% with Jsc = 34.52 mA cm-2, Voc = 0.76 V, and FF = 85.1%. The results show that the variation in valence and conduction band offsets (-0.4 to +0.2 eV and -0.4 to +0.57 eV) at the ETL/absorber and absorber/HTL interfaces dominate the SC performance. Also, different absorber defect densities (1 × 1014-1 × 1020 cm-3) and thicknesses (200-3000 nm) effectively influence the PCE. Moreover, simulated impedance spectroscopy (IS) data (through SCAPS-1D) were fitted using equivalent electrical circuits to extract relevant parameters, including Rs, RHF, and RLF, allowing us to better discuss the physics of the device. The fitted IS results strongly revealed that enhanced SC performance is associated with higher recombination resistance and a larger recombination lifetime. Likewise, a slight variation in the Rs (0 to 2.5 Ω cm2) highly impacts the PCE (22.5% to 19.7%). Furthermore, a tandem cell is designed by combining the top cell of ethylenediammonium-FASnI3 perovskite with the FA4GeSbCl12 bottom cell using a filtered spectrum strategy, which opens the door for multi-junction SC applications. These findings firmly reveal that the appropriate energy level alignment at interfaces with suitable material properties is the key to boosting SC performance.
