Simultaneous biodegradation of BTX by isolated degrading bacterial strains in a newly designed modulated bio-scrubber assisted to airlift parallel bioreactors.

A new approach in this present study, isolated bacteria from refinery sludge were used in a laboratory-scale bio-scrubber, connecting with two parallel airlift bioreactors to eliminate harmful and toxic fumes of BTX. One of the main features of this bio-scrubber is using porous mineral pumice fillers (Lava Rock) inside poly-urethane foam (PUF) module tower, connecting with agitator bio-phasic continuously stirred tank bio-reactor (CSTbR) to increase retention time and contact surface. The bio-scrubber and airlift plug flow bio-reactor (PFbR) were used in parallel with cooling flow to be more efficient in preservation of the corresponding heater and endothermic from removal reactions. Performance of bio-scrubber in removing BTX vapors with 10 % silicone oil and grade 350 poise as organic phase in the inlet concentration range of 180 ± 0.3 to 1950.5 ± 0.1 mg /m3 (ppmv) for up to 6 months in two air flow rate's 2.5 and 3.5 (lit/min) that each treatment lasted about 2 months. The rate of biodegradation in this study was carried out by mixing 3 isolated bacteria, obtaining from refinery sludge, named DBIS-03, DTIS-12, and DXIS-09, which they had highest biodegradability than all the isolated strains. The results of BTX biodegradation at each EBRT (Empty Bed Retention Time) showed that the removal efficiency of BTX with isolated bacterial samples was able to grow and multiply on porous fillers and regenerate the growth medium of autotrophic bacterial strain with O2 gas and micronutrients from contaminated air flow with minimum concentration. Benzene, toluene and xylene inputs maximum concentration over a period of 20 days loading, respectively: B :99.2 % (at 2.5 lit/min and 183.2 ± 0.2 mg /m3 (ppmv)), T: 98 % (at 2.5 lit/min and 327.1 ± 0.1 mg /m3 ( ppmv)) and X: 85.9 % (at 2.5 lit/min and 296.8 ± 0.8 mg /m3 (ppmv)) compared to 3.5 lit/min and so show the best performance in removing BTX from polluted air in period of 30 days.

Molecular separation of ions from aqueous solutions using modified nanocomposites.

Herein, two novel porous polymer matrix nanocomposites were synthesized and used as adsorbents for heavy metal uptake. Methacrylate-modified large mesoporous silica FDU-12 was incorporated in poly(methyl methacrylate) matrix through an in-situ polymerization approach. For another, amine-modified FDU-12 was composited with Nylon 6,6 via a facile solution blending protocol. Various characterization techniques including small-angle X-ray scattering, FTIR spectroscopy, field emission-scanning electron microscopy, transmission electron microscopy, porosimetry, and thermogravimetric analysis have been applied to investigate the physical and chemical properties of the prepared materials. The adsorption of Pb(II) onto the synthesized nanocomposites was studied in a batch system. After study the effect of solution pH, adsorbent amount, contact time, and initial concentration of metal ion on the adsorption process, kinetic studies were also conducted. For both adsorbents, the Langmuir and pseudo-second-order models were found to be the best fit to predict isotherm and kinetics of adsorption. Based on the Langmuir model, maximum adsorption capacities of 105.3 and 109.9 mg g-1 were obtained for methacrylate-modified FDU-12/poly(methyl methacrylate) and amine-modified FDU-12/Nylon 6,6, respectively.

Study on novel modified large mesoporous silica FDU-12/polymer matrix nanocomposites for adsorption of Pb(II).

In this study, porous methacrylate-modified FDU-12/poly(methyl methacrylate) and amine-modified FDU-12/Nylon 6 nanocomposites were synthesized via a facile solution casting protocol. The physicochemical properties of the prepared materials were studied using various characterization techniques including Fourier transform-infrared spectroscopy, field emission-scanning electron microscopy, transmission electron microscopy, and nitrogen adsorption/desorption. After characterization of the materials, the prepared nanocomposites were applied as novel adsorbents for the removal of Pb(II) from aqueous media. In this regard, the effect of various parameters including solution pH, adsorbent amount, contact time, and initial concentration of Pb(II) on the adsorption process was investigated. To study the mechanism of adsorption, kinetic studies were conducted. The kinetic models of pseudo-first-order, pseudo-second-order, Elovich, and intraparticle diffusion were employed. The results revealed that the adsorption of Pb(II) onto methacrylate-modified FDU-12/poly(methyl methacrylate) and amine-modified FDU-12/Nylon 6 adsorbents followed the pseudo-second-order kinetic model. Also, different isotherms including Langmuir, Freundlich, and Dubinin-Radushkevich were applied to evaluate the equilibrium adsorption data. Langmuir isotherm provided the best fit with the equilibrium data of both adsorbents with maximum adsorption capacities of 99.0 and 94.3 mg g-1 for methacrylate-modified FDU-12/poly(methyl methacrylate) and amine-modified FDU-12/Nylon 6, respectively, for the removal of Pb(II).

Subcritical water liquefaction of oil palm fruit press fiber in the presence of sodium hydroxide: an optimisation study using response surface methodology.

Thermal decomposition of oil palm fruit press fiber (FPF) into a liquid product (LP) was achieved using subcritical water treatment in the presence of sodium hydroxide in a high pressure batch reactor. This study uses experimental design and process optimisation tools to maximise the LP yield using response surface methodology (RSM) with central composite rotatable design (CCRD). The independent variables were temperature, residence time, particle size, specimen loading, and additive loading. The mathematical model that was developed fit the experimental results well for all of the response variables that were studied. The optimal conditions were found to be a temperature of 551 K, a residence time of 40 min, a particle size of 710-1000 microm, a specimen loading of 5 g, and a additive loading of 9 wt.% to achieve a LP yield of 76.16%.

Sub/supercritical liquefaction of oil palm fruit press fiber for the production of bio-oil: effect of solvents.

Thermal decomposition of oil palm fruit press fiber (FPF) with sub/supercritical methanol, ethanol, acetone, and 1,4-dioxane treatments were investigated using a high-pressure autoclave reactor. When FPF was decomposed with methanol, ethanol, and acetone from 483 to 603 K, the highest degree of conversion obtained were 81.5%, 77.8%, and 67.9% while the highest liquid product yield (LP) obtained were 38.0%, 36.9%, and 38.5%, respectively. For the case of 1,4-dioxane, the conversion of FPF increased from 18.30% to 80.00%, while LP yield increased dramatically from 13.30% to 50.90% (consisting of 42.3% bio-oil compounds) when the reaction temperature was increased from 483 to 563 K. However, the conversion of FPF and LP yield decreased to 69.60% and 24.10%, respectively, when the temperature was further increased to 603 K. Comparison between all the solvents, subcritical 1,4-dioxane treatment was found very effective in the degradation of FPF to produce bio-oil component.

Subcritical water liquefaction of oil palm fruit press fiber for the production of bio-oil: effect of catalysts.

Decomposition of oil palm fruit press fiber (FPF) to various liquid products in subcritical water was investigated using a high-pressure autoclave reactor with and without the presence of catalyst. When the reaction was carried in the absence of catalyst, the conversion of solid to liquid products increased from 54.9% at 483 K to 75.8% at 603 K. Simultaneously, the liquid yield increased from 28.8% to 39.1%. The liquid products were sub-categorized to bio-oil (benzene soluble, diethylether soluble, acetone soluble) and water soluble. When 10% ZnCl(2) was added, the conversion increased slightly but gaseous products increased significantly. However, when 10% Na(2)CO(3) and 10% NaOH were added independently, the solid conversion increased to almost 90%. In the presence of catalyst, the liquid products were mainly bio-oil compounds. Although solid conversion increased at higher reaction temperature, but the liquid yield did not increase at higher temperature.