Comparative Study Effect of Urea-Sulfur Fertilizers on Nitrogen Uptake and Maize Productivity.

Combined nitrogen (N) and sulfur (S) fertilization is a good management strategy to reduce N loss and increase the efficiency of N fertilizers to achieve high grain yields and quality. Field trials for 2 yrs. (2018-2019) were conducted to evaluate the comparative advantage of conventional urea (150 N kg ha-1) compared to urea+ ammonium sulfate (150 N kg ha-1), urea+ calcium sulfate (150 N kg ha-1), and urea cocrystals (CaSO4.4urea) (150 N kg ha-1) when applied as nitrogen fertilizers to the maize. The statistics show a significant treatments effect on developed corn cobs, fresh and dry cob yields and grain yield, with 1000 grains with better results in 2019 than in 2018. The fertilization treatments affected grain yields significantly for 2018 and 2019, respectively. Urea+ ammonium sulfate and urea cocrystal provided a significant increase in grain yields by 10.5% and 7.50%, respectively, compared to urea in 2018, w1hereas, in 2019, urea cocrystal supplied the grain yields with a significant increase of 23.07% compared to urea, followed by urea + calcium sulfate which provided a 10.46% increase compared to urea. The study highlights that using urea-sulfur fertilizers enhanced the release of mineral nitrogen in the soil, improved the grain's N uptake by the plant and increased maize grain yields.

Chemical composition and risk assessment of spring barley grown in artificially contaminated soil.

A model contaminated system was developed to determine mechanisms of napthalene bioaccumulation and effect on the mineral composition of spring barley grain and straw grown in the Calcari-Endohypogleyic Luvisol. The soil was mixed with green waste compost and spiked with naphthalene which concentration varied from 0 to 500 ppm. Obtained results indicate that naphthalene additive at the concentration rate from 100 to 500 ppm reduced spring barley germination. The significant lower weight of green mass per pot, one plant weight and mass of 1000 grains were observed in the amendment with the highest naphthalene concentration (500 ppm). It was determined the daily intake (ED) of 16PAHs via spring barley grain and incremental lifetime cancer risks (ILCR). Estimated ED and ILCR of 16PAHs via spring barley ranged from 1.00 to 3.78 ng day-1 and 3.79 to 14.3 × 10-5 respectively. It should be noted that obtained results are higher around 10 times compared to previous studies performed using wheat grain. This study presents the mechanisms of naphthalene bioaccumulation and effect on the mineral composition of the most common agricultural plant spring barley grain and straw. Spring barley grain was found to have a higher content of nitrogen (N), boron (B) and phosphorous (P), whereas straw had a higher content of potassium (K), sodium (Na), chromium (Cr) and calcium (Ca).

Granulated biofuel ash as a sustainable source of plant nutrients.

Recovery of nutrients from biomass combustion ash is of great importance for sustainable bioenergy waste use. In this work, granulated fertilizer materials were engineered from biofuel bottom ash, lime kiln dust and water, analysed for their chemical complexity and tested in pot experiments (2017-2018) for their propensity to release nutrients. The results obtained in this work showed that spring barley yield was observed to be the highest for granulated biomass ash with 30% of ash in the granule. The yield increased 3.99 t ha-1 per 100 kg ha-1 potassium oxide (K2O) in 2017 and 1.23 t ha-1 per 100 kg ha-1 K2O in 2018. Straw yield varied between 1.39-5.08 t ha-1/100 kg ha-1 in 2017 and 0.36-1.23 t ha-1/100 kg ha-1 in 2018. Calcium concentration significantly increased in soil. No significant changes in soil mobile phosphorus (P) were obtained as well as for the heavy metal concentrations in soil. This suggests that biofuel ash can be a significant source of certain major nutrients for crops that can also beneficially affect soil pH. The results of this work can provide policy-makers with the information needed to diversify existing and enable new biomass bottom ash utilization routes which currently vary significantly between the countries.

Screening of chemical composition and risk index of different origin composts produced in Lithuania.

The application of composts could be accompanied by potential hazards to soil and humans, caused by heavy metals and organic persistent pollutants. A total of 115 compost samples from four different origins (green waste composts, sewage sludge composts, mixed municipal waste composts after mechanical-biological treatment and mixed municipal waste compost) were collected to analyse the chemical composition, nutrients levels, seven heavy metals, 15 polycyclic aromatic hydrocarbons (PAHs) and seven polychlorobiphenyls (PCBs). Simulation models were used to estimate the heavy metal accumulation risk in soil and to evaluate the potential ecological risk to environment. After analysing chemical parameters of compost quality, it was found that sewage sludge composts contained the highest amounts of nitrogen (2.98%), phosphorus (4.44%) and organic matter (47.6%), and the highest potassium content (1.20%) was found in mixed municipal composts after mechanical-biological treatment. After having tested all the composts, green waste composts had the lowest content of the following nutrients: nitrogen, phosphorus, potassium and sulphur. High molecular weight PAHs dominated in green waste, sewage sludge and mixed municipal waste composts, and the opposite tendency was observed on mixed municipal waste composts after mechanical-biological treatment; low molecular weight PAHs were abundant. It was determined that, according to the total amount of 15 PAHs (16.54 mg kg-1 d.w.) and 7 PCBs (233.53 µg kg-1 d.w.), the most contaminated composts were produced from mixed municipal waste. As it was expected, the lowest level of PCBs (13.85 µg kg-1 d.w.) was found in green waste composts. Monte Carlo simulations showed that the shortest period in which zinc concentration in soil could increase twice is 2 years when applying continuously mixed municipal waste compost after mechanical-biological treatment. Based on Monte Carlo simulation results from repeated application of green waste composts, mixed municipal waste compost and mixed municipal waste compost after mechanical-biological treatment could double the soil background level of copper in 6 and 3 years respectively. Reducing the content of heavy metals in composts would be of great significance for minimising the damage caused by them.