ABSTRACT
Ultrafiltration has been used to examine the size fractionation of lead, copper, iron, aluminium, calcium, potassium and sodium in white and red wines. Fractionation patterns demonstrated that the behaviour of lead is significantly diferent to the other metals considered. In red wine, there was a sudden decrease for lead between 100 000 and 30 000 nominal molecular weight cut off (NMWCO) and in white wine, a gradual decrease in the lead concentration was observed from 100 000 NMWCO. Iron was the only other metal which showed, for red wine, a size distribution pattern with a reduction in the iron concentration between 30 and 50% from 100 000 to 1000 NMWCO. Potential binding agents for lead and iron are discussed. The absence of any fractionation pattern for the other metals examined has been interpreted in terms of the metals existing as aquated cations (potassium and sodium), metal tartrate complexes (aluminium, copper and calcium) and either tartrate or phosphate for iron in white wine. The possibility of ultrafiltration disturbing kinetically facile processes, particularly for copper and calcium, is identified.
ABSTRACT
Behavioural observations were made on 150 3-week weaned pigs housed in pens with fully perforated floors, or a solid-floored lying area with or without straw. Observations were made during a period of high ambient temperatures and during cool weather. At high ambient temperatures pigs with part-solid floors defaecated and urinated in the lying area and showed a higher (P less than 0.01) incidence of rooting behaviour associated with wallowing. Pigs on fully perforated floors showed reduced levels of activity in hot conditions (P less than 0.01). Pigs given straw were more active (P less than 0.01) and spent 25% of active behaviour in straw directed behaviour. There was a higher incidence (P less than 0.01) of oral behaviour directed at penmates and pen fittings amongst pigs housed on fully perforated floors.
