ABSTRACT
The presence of harmful substances such as dyes in water systems poses a direct threat to the quality of people's lives and other organisms living in the ecosystem. Orange G (OG) is considered a hazardous dye. The existing paper attempts to evaluate a low-cost adsorbent for the effective removal of OG dye. The developed adsorbent Polyaniline@Hydroxyapatite extracted from Cilus Gilberti fish Scale (PANI@FHAP) was elaborated through the application of the in situ chemical polymerization method to incorporate PANI on the surface of naturally extracted hydroxyapatite FHAP. The good synthesis of PANI@FHAP was evaluated through multiple techniques including X-ray diffraction (XRD), Scanning electron microscopy coupled with energy dispersive X-ray spectrometry (SEM/EDS), Fourier Transforms Infrared spectroscopy (FTIR), and thermogravimetric analysis (TGA) coupled with thermal differential analysis (DTA) analysis. The results reveal a highly ordered disposition of PANI chains on FHAP, resulting in a well-coated FHAP in the PANI matrix. Furthermore, the presence of functional groups on the surface of PANI such as amine (-NH2) and imine (=NH) groups would facilitate the removal of OG dye from contaminated water. The adsorption of OG onto PANI@FHAP was conducted in batch mode and optimized through response surface methodology coupled with box-Behnken design (RSM/BBD) to investigate the effect of time, adsorbent dose, and initial concentration. The outcomes proved that OG adsorption follows a quadratic model (R2 = 0.989). The kinetic study revealed that the adsorption of OG fits the pseudo-second-order model. On the other hand, the isotherm study declared that the Freundlich model is best suited to the description of OG adsorption. For thermodynamic study, the adsorption of OG is spontaneous in nature and exothermic. Furthermore, the regeneration-reusability study indicates that PANI@FHAP could be regenerated and reused up to five successive cycles. Based on the FTIR spectrum of PANI@FHAP after OG adsorption, the mechanism governing OG adsorption is predominantly driven by π-π interaction, electrostatic interaction, and hydrogen bonding interactions. The obtained results suppose that PANI@FHAP adsorbent can be a competitive material in large-scale applications.
ABSTRACT
The use of fish waste as a source material for the development of functional beads has significant potential applications in the fields of materials science and environmental sustainability. In this study, a biomaterial bead of chitosan was cross-linked with bio-hydroxyapatite (Bio-Hap/Cs) through the encapsulation process to create a stable and durable material. The beads are characterized using scanning electron microscopy combined with energy dispersive X-ray spectrometry, Fourier transform infrared spectroscopy, and X-ray diffraction techniques. The adsorption efficiency of Bio-Hap/Cs hydrogel beads was evaluated by using Orange G (OG) dye in both batch and recirculating column systems, and the effect of various parameters on the adsorption capacity was investigated. In the batch study, it was found that OG removal increased with an increasing pH and adsorbent dose. However, in the recirculating column system, a higher bed height and lower flow rate led to increased removal of the OG dye. The kinetic study indicated that the pseudo-second-order model provided a good description of OG adsorption onto Bio-Hap/Cs beads in both batch and recirculating processes, with a high coefficient correlation. The maximum adsorbed amounts are found to be 19.944 mg g-1 and 9.472 mg g-1 in batch and recirculating processes, respectively. Therefore, Bio-Hap/Cs hydrogel beads have demonstrated an effective and reusable material for OG dye remediation from aqueous solutions using recirculating adsorption processes.
