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1.
PLoS One ; 19(1): e0297372, 2024.
Article in English | MEDLINE | ID: mdl-38265991

ABSTRACT

Expanded polystyrene (EPS) bead lightweight soil composites are a new type of artificial geotechnical material with low density and high strength characteristics that can be widely used in engineering projects. To promote the wide application of EPS bead lightweight soil in engineering, when slag is used to replace part of the cement as a binding agent, it can better improve the effect of soil and reduce engineering costs. The mechanical properties of EPS lightweight soil mixed with slag were analyzed by conducting an unconfined compressive strength (UCS) test and triaxial test on lightweight soil with different EPS bead contents and slag contents. The particle sizes of the EPS beads are 1~3 mm, the EPS contents are 1%, 2%, 3%, and 4%, and the slag-cement composite binding agents are 10%, 15%, 20% and 25%. The results show that the UCS decreases significantly with increasing EPS bead content at different EPS bead contents and slag contents; the UCS of the specimen with 30% slag content is the largest; and the UCS of lightweight soil without slag is comparable to that of lightweight soil with a slag content of approximately 60%. The peak stress in triaxial increases with increasing confining pressure, and the modulus of deformation decreases linearly with increasing EPS bead content. the slag-cement composite binding agent has a significantly better reinforcing effect than single mixed cement. The stress‒strain curves of EPS lightweight soil mixed with slag exhibits hardening and softening characteristics. EPS bead content and slag content determine the stress‒strain characteristics of the EPS lightweight soil mixed with slag. The macromechanical properties based on the microscopic mechanism of the EPS lightweight soil mixed with slag shows that different slag contents affect the failure pattern of EPS lightweight soil mixed with slag. The research results can provide a reference for engineering design and application.


Subject(s)
Bone Cements , Polystyrenes , Compressive Strength , Engineering , Glass Ionomer Cements , Soil
2.
ACS Omega ; 8(34): 31365-31372, 2023 Aug 29.
Article in English | MEDLINE | ID: mdl-37663457

ABSTRACT

In seasonally frozen regions, the bearing capacity of soil decreases and gradually deteriorates after undergoing freeze-thaw cycles. To resolve this problem, based on the idea of frost-resistant filling materials, a filling scheme of expanded polystyrene (EPS) particles lightweight soil in cold regions was proposed. Unconfined compressive strength, direct shear, and micro-SEM tests were carried out to study the physical and mechanical properties of EPS particles lightweight soil under freeze-thaw cycles. The results indicate that the EPS particle lightweight soil has good frost resistance and can be used as frost-resistant filling material in cold regions. Under freeze-thaw cycles, EPS particle lightweight soil maintains good integrity; EPS particles can effectively reduce the frost heave rate, mass loss rate, and compressive strength loss rate of lightweight soil. The compressive strength depends on the EPS and cement contents: it decreases with an increase in the EPS content and increases with an increase in the cement content. The strength loss rate decreases with an increase in both. When the content of EPS is larger (more than 2%), the soil cement bound with EPS particles is limited, and the performance of lightweight soil decreases. The shear strength and cohesion decrease with an increase in freeze-thaw cycles and EPS content, and the internal friction angle follows no obvious rule with regard to the increase in freeze-thaw cycles but decreases with an increase in the EPS content. Based on the experimental results, an empirical formula for the compressive strength of EPS particle lightweight soil under freeze-thaw cycles was proposed. This study can provide a reference for the engineering design and application and provide new ideas for resolving freeze-thaw problems in construction engineering in cold regions.

3.
Nanoscale Adv ; 3(18): 5312-5321, 2021 Sep 14.
Article in English | MEDLINE | ID: mdl-36132625

ABSTRACT

Ti3C2T x is a promising new two-dimensional layered material for supercapacitors with good electrical conductivity and chemical stability. However, Ti3C2T x has problems such as collapse of the layered structure and low pseudocapacitance. In this paper, we propose Bi2O3-Ti3C2T x nanocomposites prepared by a solvothermal method, study the impact of Bi2O3 loading on the phase state and microstructure, and evaluate the electrochemical performance of Bi2O3-Ti3C2T x . Studies have shown that spherical Bi2O3 particles were uniformly dispersed in the interlayer and surface of Ti3C2T x , which enlarged the interlayer spacing of the Ti3C2T x and increased the pseudocapacitance. When the mass percentage of Bi2O3 and Ti3C2T x was 30% (TB30), the specific capacity of TB30 was as high as 183 F g-1 at a current density of 0.2 A g-1, which was about 2.8 times that of Ti3C2T x (TB0). Moreover, a typical asymmetric supercapacitor device assembled with TB0 as the positive electrode and TB30 as the negative electrode exhibited a high energy density of 3.92 W h kg-1 and a maximum power density of 36 000 W kg-1 and maintained 77.4% of the initial capacitance after 5000 cycles at a current density of 2 A g-1. Therefore, the Bi2O3-Ti3C2T x as the negative electrode of supercapacitor has broad application prospects in the field of energy storage.

4.
Opt Express ; 24(26): 30264-30274, 2016 Dec 26.
Article in English | MEDLINE | ID: mdl-28059302

ABSTRACT

In this paper, we propose a replication method of thermoplastic polymer spherical lens array using a novel microforged mold. The Si3N4 ceramic balls, with 3.5 mm diameter, 10 nm surface roughness and 84 nm deviation from spherical profile, were utilized as indentor to generate aluminum alloy lens array mold. Upon the optimization of technical parameters, such as heating and de-molding temperature, indentation force and holding time, a high quality spherical lens array mold was obtained. The mold was used to fabricate spherical PMMA lens array by hot embossing, which showed excellent characteristics on dimensional stability, surface features and optical performances. Especially for the requirements of deep sag height and low f/#, the microforging technique reveals superior performance for low cost and high quality manufacture of spherical lenses. Compared to the previous complicated tools which requires precise calibration, the self-alignment mode of the balls and cavities can easily guarantee positioning accuracy. Accordingly, the pre-milled spherical cavity deformed uniformly in the process of microforging due to the symmetrical distribution of contact pressure and reduced the error caused by deformation. We believe the proposed microforging technique is an ideal mass production approach to the fabrication of thermoplastic polymer spherical lens array.

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