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1.
J Chromatogr Sci ; 47(9): 804-7, 2009 Oct.
Article in English | MEDLINE | ID: mdl-19835693

ABSTRACT

Essential oil compositions of aerial parts from two species in the Piper (Piperaceae family) genera: Piper lanceaefolium Kunth and Piper hispidum Sw., frequently called deflated (for the anti-inflammatory activity) or cord. Piperaceae leaves were collected in different regions of the Chocó department in northwestern Colombia and identified by botanists from Colombian National Herbarium, where a voucher of each specimen were deposited (No- COL 519993 and No- COL 519969, respectively). The essential oils were obtained by microwave-assisted hydrodistillation (MWHD) and analyzed by gas chromatography-mass spectrometry (GC-MS). The P. lanceaefolium essential oil was sesquiterpenoid type (71.7%). This composition was represented by sesquiterpenes hydrocarbons (58.5%) and by their oxygenated derivates (13.2%); the main compounds were, trans-beta-caryophyllene (11.6%) and germacrene D (10.7%) followed by alpha-selinene (7.8%), beta-pinene (5.4%), beta-selinene (4.8%), and alpha-cubebene (4.3%). The Piper hispidum essential oil also was sesquiterpene type (74.4%) and oxygenated sesquiterpenes (46.4%) followed by sesquiterpenes hydrocarbons (28.0%). The main compounds were trans-nerolidol (23.6%) and caryophyllene oxide (5.4%) followed by beta-elemene (5.1%), trans-beta-caryophyllene (5.1%), curzerene (4.9%), and germacrene B (4.5%). Trans-beta-caryophyllene presents the higher percentage of the common compounds in the two species' essential oil (11.6% and 5.1% in P. lanceaefolium and P. hispidum, respectively).


Subject(s)
Oils, Volatile/analysis , Piperaceae/chemistry , Plant Oils/analysis , Colombia
2.
J Chromatogr Sci ; 47(9): 800-3, 2009 Oct.
Article in English | MEDLINE | ID: mdl-19835692

ABSTRACT

Essential oils chemical constituents of leaves of O. gratissimum and O. campechianum of the Lamiaceae family, collected in Chocó of northwest Colombian, were obtained by microwave-assisted hydrodistillation and analyzed by gas chromatography coupled with mass spectrometry. A total of 33 and 37 compounds were identified in the essential oil of O. gratissimum and O. campechianum, respectively. O. gratissimum's main essential oils were eugenol (43.2%), 1,8-cineole (12.8%) and beta-selinene (9.0%); in the O. campechianum essential oil, the main components were methyl eugenol (12.0%), germacrene D (10.1%), and eugenol (9.0%). Main distribution of compounds in these essential oils are 25.0% monoterpenes hydrocarbons, 15.0% monoterpenes oxygenated, 35.0% sesquiterpenes hydrocarbons, 7.5% other oxygenated components for O. gratissimum, 33.9% sesquiterpenes hydrocarbons, and 10.7% their respective oxygenated derivates; for O. campechianum, the distribution was 10.7% monoterpenes hydrocarbons and 7.1% their respective oxygenated derivates and 3.6% phenylpropanes. According to the essential oils chemical composition of Ocimum gratissimum and O. campechianum, they are classified as eugenol and methyl eugenol chemotype, respectively.


Subject(s)
Eugenol/analogs & derivatives , Eugenol/chemistry , Ocimum/chemistry , Oils, Volatile/chemistry , Plant Oils/chemistry , Colombia , Plant Leaves/chemistry
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