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2.
Bioresour Technol ; 100(2): 737-43, 2009 Jan.
Article in English | MEDLINE | ID: mdl-18757197

ABSTRACT

The graft polymerization reaction between ethylene carbonate (EC) and scots pine sawdust (SPS) or peat moss (PM) offers a solvent-free approach to the simple and inexpensive aliphatic derivatization of these lignocellulosic fibers. This reaction was studied with liquid or vapor EC phases in three different reactor configurations: batch stirred (BSR), semi-continuous stirred (SSR) and continuous tubular in the gas phase (CVTR). The use of a vapor phase allowed a satisfactory grafting yield and minimal production of non-grafted polyol by-products. The crosslinking agent 4,4'-methylenebis(phenylisocyanate) (MDI) achieved superior characteristics to form shaped tablets resistant to water disaggregation, a high water retention capacity and high compression strength, characteristics that conventional organic supports like PM or PM-polyurethane foam mixtures used in biofiltration of waste gases do not completely possess.


Subject(s)
Dioxolanes/chemistry , Gases/isolation & purification , Membranes, Artificial , Organic Chemicals/isolation & purification , Soil , Ultrafiltration/methods , Wood/chemistry , Elasticity , Polymers/chemistry , Stress, Mechanical
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