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Chem Commun (Camb)
; 58(64): 8998-9001, 2022 Aug 09.
Article
in English
| MEDLINE
| ID: mdl-35861624
ABSTRACT
A bicyclic pyrone-type species on oxygen-doped carbon catalysts was identified as the active site for the oxygen reduction reaction in acidic solution. It has much higher activity than that of typical nitrogen-doped carbon catalysts (0.219 e s-1 site-1vs. 0.021-0.088 e s-1 site-1 at 0.6 VRHE). The ortho-carbon atom in the carbonyl ring of the pyrone-type species was revealed as the reactive site by theoretical calculations.