ABSTRACT
The aim of this work was to compare the concentration of glyphosate and AMPA in the PM10 and the actual PM10 emission from agricultural soils and unpaved roads, located inside and outside farm fields. To determine the actual PM10 emission by wind erosion, the actual wind erosion was estimated using the Wind Erosion Equation, and the PM10 emission efficiency was measured with the Easy Dust Generator. PM10 was collected in an electrostatic precipitator coupled to the Easy Dust Generator. Actual PM10 emission was 11.5 g ha-1 year-1 in agricultural soils and 4711.4 g ha-1 year-1 in unpaved roads. The high value of actual PM10 emission in unpaved roads was due to their high actual wind erosion and the high PM10 emission efficiency, while the low value in agricultural soils was due to their low actual wind erosion. Content of glyphosate in the PM10 ranged from 59 to 359 µg kg-1 in agricultural soils, from 382 to 454 µg kg-1 in unpaved roads inside farm fields, and from 39 to 639 µg kg-1 in unpaved roads outside farm fields. Content of AMPA in the PM10 ranged from 387 to 7228 µg kg-1 in agricultural soils, from 900 to 4138 µg kg-1 in unpaved roads inside farm fields, and 98 to 500 µg kg-1 in unpaved roads outside farm fields. AMPA concentration in PM10 was higher than that of glyphosate due to the longer persistence of AMPA than glyphosate. Glyphosate and AMPA concentrations in PM10 were higher than in soil, which is an additional risk that should be considered when the effect of PM10 emitted by agricultural soils and unpaved roads on human health are evaluated. Our results show that the amount and chemical composition of PM10 emitted by wind erosion from unpaved roads should be studied in other regions.
ABSTRACT
Wind erosion of freshly-deposited volcanic ash causes persistent storms, strongly affecting ecosystems and human activity. Wind erosion of the volcanic ash was measured up to 17 months after the ash deposition, at 7 sites located within the ash-deposition area. The mass flux was measured up to 1.5 m above ground level. Mass transport rates were over 125 times the soil wind-erosion rates observed before the ash deposition, reaching up to 6.3 kg m-1 day-1. Total mass transport of ash during the 17 months ranged between 113.6 and 969.9 kg m-1 depending on topographic location and wind exposure. The vertical distribution of the mass flux at sites with higher vegetation cover was generally inverted as compared to sites with lower vegetation cover. This situation lasted 7 months and then a shift towards a more uniform vertical distribution was observed, in coincidence with the beginning of the decline of the mass transport rates. Decay rates differed between sites. Despite changes over time, an inverse linear correlation between the mass transports and the mass-flux gradients was found. Both the mass-flux gradients and the average mass-transport rates were not linked with shear-stress partition parameters, but with the ratio: ash-fall thickness to total vegetation cover.
