Breaking Fundamental Limitation of Flow-Induced Anisotropic Growth for Large-Scale and Fast Printing of Organic Single-Crystal Films.

Advanced organic electronic technologies have put forward a pressing demand for cost-effective and high-throughput fabrication of organic single-crystal films (OSCFs). However, solution-printed OSCFs are typically plagued by the existence of abundant structural defects, which pose a formidable challenge to achieving large-scale and high-performance organic electronics. Here, it is elucidated that these structural defects are mainly originated from printing flow-induced anisotropic growth, an important factor that is overlooked for too long. In light of this, a surfactant-additive printing method is proposed to effectively overcome the anisotropic growth, enabling the deposition of uniform OSCFs over the wafer scale at a high speed of 1.2 mm s-1 at room temperature. The resulting OSCF exhibits appealing performance with a high average mobility up to 10.7 cm2 V-1 s-1, which is one of the highest values for flexible organic field-effect transistor arrays. Moreover, large-scale OSCF-based flexible logic circuits, which can be bent without degradation to a radius as small as 4.0 mm and over 1000 cycles are realized. The work provides profound insights into breaking the limitation of flow-induced anisotropic growth and opens new avenues for printing large-scale organic single-crystal electronics.

Probing non-equilibrium inner structure of polymeric nanoparticle via aggregation-induced emission of luminogen.

A molecular segregation inside a nanoparticle was crucial for its properties but usually hard to be determined, especially for organic particles. Herein, non-equilibrium polymeric nanoparticles loading a luminogen via an aggregation-induced emission (AIE) were prepared via an instant formation process, flash nanoprecipitation (FNP). Small organic molecules, polymeric excipients, and oily compounds were used as coprecipitants to reveal effects of conjugate moiety, glass transition temperature (Tg), and a condensed state of a coprecipitant on the fluorescence (FL) intensity of the suspension. The results indicated that the addition of a small molecule in a solid state without any conjugate moiety or a polymeric excipient with high Tg would facilitate enhancing the FL intensity, while a coprecipitant with a conjugate moiety or low Tg or in liquid would decrease the intensity. Moreover, this study revealed that the nanoparticle formed via FNP had a randomly packed inner structure where different compositions tended to evenly distribute inside rather than a micellar structure with a phase-separated core-shell one. These findings provided a guide to selecting a suitable coprecipitant for AIE-luminogen nanoparticles in applications. The developed probing method would also benefit for better understanding the particle formation kinetics in FNP.