ABSTRACT
In this work, carbonization and subsequent activation procedures were adopted to synthesize waste shea butter shells into oxygen-rich interconnected porous activated carbon (SAC_x, x is the mass ratio of KOH used for activation). The SAC_1.5 electrode material showed outstanding electrochemical performance with high specific capacitance (286.6F/g) and improved rate capability, owing to various synergistic effects originating from a high specific surface area (1233.5â¯m2/g) and O-rich content. The SAC_1.5-based symmetric device delivered an impressive specific capacitance of 91.6F/g with a high energy density of 12.7 Wh/kg at 0.5 A/g. The device recorded 99.9â¯% capacitance retention after 10,000 charge-discharge cycles. The symmetric supercapacitor device successfully lit an LED bulb for more than 1â¯h, signifying the potential of bio-waste as an efficient carbon precursor for electrode material in practical supercapacitors. This work offers an efficient, affordable, and environmentally friendly strategy for potential renewable energy storage devices.
ABSTRACT
A new, sizable family of 2D transition metal carbonitrides, carbides, and nitrides known as MXenes has attracted a lot of attention in recent years. This is because MXenes exhibit a variety of intriguing physical, chemical, mechanical, and electrochemical characteristics that are closely linked to the wide variety of their surface terminations and elemental compositions. Particularly, MXenes are readily converted into composites with materials including oxides, polymers, and CNTs, which makes it possible to modify their characteristics for a variety of uses. MXenes and MXene-based composites have demonstrated tremendous promise in environmental applications due to their excellent reducibility, conductivity, and biocompatibility, in addition to their well-known rise to prominence as electrode materials in the energy storage sector. The remarkable characteristics of 2D MXene, including high conductivity, high specific surface area, and enhanced hydrophilicity, account for the increasing prominence of its use in storage devices. In this review, we highlight the most recent developments in the use of MXenes and MXene-based composites for electrochemical energy storage while summarizing their synthesis and characteristics. Key attention is paid to applications in supercapacitors, batteries, and their flexible components. Future research challenges and perspectives are also described.
ABSTRACT
Supercapacitors may be able to store more energy while maintaining fast charging times; however, they need low-cost and sophisticated electrode materials. Developing innovative and effective carbon-based electrode materials from naturally occurring chemical components is thus critical for supercapacitor development. In this context, biopolymer-derived porous carbon electrode materials for energy storage applications have gained considerable momentum due to their wide accessibility, high porosity, cost-effectiveness, low weight, biodegradability, and environmental friendliness. Moreover, the carbon structures derived from biopolymeric materials possess unique compositional, morphological, and electrochemical properties. This review aims to emphasize (i) the comprehensive concepts of biopolymers and supercapacitors to approach smart carbon-based materials for supercapacitors, (ii) synthesis strategies for biopolymer derived nanostructured carbons, (iii) recent advancements in biopolymer derived nanostructured carbons for supercapacitors, and (iv) challenges and future prospects from the viewpoint of green chemistry-based energy storage. This study is likely to be useful to the scientific community interested in the design of low-cost, efficient, and green electrode materials for supercapacitors as well as various types of electrocatalysis for energy production.
Subject(s)
Carbon , Biopolymers , Carbon/chemistry , Electric Capacitance , Electrodes , PorosityABSTRACT
BACKGROUND: Underground miners can experience occupational health diseases due to exposure to particulate matter hazards. OBJECTIVES: The aim of the present study was to examine occupational exposures of underground miners to dust and diesel particulate matter and to identify exposure groups with high potential to develop associated health effects due to the presence of dust and diesel particulate matter (DPM) hazards in an underground gold mine in Ghana. METHODS: Purposive sampling was employed using gravimetric air samplers over an 8-hour time weighted average period. The National Institute for Occupational Safety and Health (NIOSH) analytical Chapter Q and 5040 were used in determining crystalline silica dust and diesel particulate matter fractions, respectively. Structured questionnaires were administered to gather data on workers' level of awareness to dust and DPM exposures. RESULTS: It was found that 41% of the sampled groups were exposed to higher crystalline silica levels above the (NIOSH) permissible exposure limit (PEL) level of 0.05 mg/m3. For DPM, 49% of these groups had exposures above the Mine Safety and Health Administration (MSHA) PEL level of 160 µg/m3. Among the 94 mine workers who responded to this study, 62% were found to be aware of the presence and hazardous nature of silica dust, 28% had minimal knowledge and the remaining were found to be unaware. CONCLUSIONS: There are varying levels of dust and DPM due to the presence of silica-bearing rocks, the production of diesel fumes and inefficiencies of available mitigation measures. Research carried out over the past decades has found confirmed cases of silicosis and lung cancer due to high dust exposure levels. Rock drillers, blast men and shotcrete operators were found to be exposed to higher levels of dust and diesel particulate matter and are at greater risk of silicosis. PARTICIPANT CONSENT: Obtained. ETHICS APPROVAL: This study was approved by the Ethics Committee of the Kwame Nkrumah University of Science and Technology, Ghana and carried out under full consent of the mining company under study. COMPETING INTERESTS: The authors declare no competing financial interests.
