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1.
PLoS One ; 16(3): e0248124, 2021.
Article in English | MEDLINE | ID: mdl-33720965

ABSTRACT

There is an increasing interest in a systemic approach to food quality. From this perspective, the copper chloride crystallization method is an interesting asset as it enables an estimation of a sample's 'resilience' in response to controlled degradation. In previous studies, we showed that an ISO-standardized visual evaluation panel could correctly rank crystallization images of diverse agricultural products according to their degree of induced degradation. In this paper we examined the role of contextual sensitivity herein, with the aim to further improve the visual evaluation. To this end, we compared subjects' performance in ranking tests, while primed according to two perceptional strategies (levels: analytical vs. kinesthetic engagement), according to a within-subject design. The ranking test consisted out of wheat and rocket lettuce crystallization images, exhibiting four levels of induced degradation. The perceptual strategy imbuing kinesthetic engagement improved the performance of the ranking test in both samples tested. To the best of our knowledge, this is the first report on the training and application of such a perceptual strategy in visual evaluation.


Subject(s)
Food Analysis , Food Quality , Crystallization , Edible Grain/chemistry , Food Analysis/methods , Humans , Lactuca/chemistry , Triticum/chemistry , Visual Perception
2.
Heliyon ; 5(1): e01102, 2019 Jan.
Article in English | MEDLINE | ID: mdl-30627687

ABSTRACT

The overall structure of dihydrate cupric chloride (CuCl2 * 2H2O) crystallization patterns in the presence of bovine serum albumin (BSA) in a Petri dish is influenced by dewetting. The dewetting behavior, which can be either before or after initial CuCl2 nucleation, depends on the amount of CuCl2 and BSA in the Petri dish. We postulate that the concentration and/or temperature gradient area in the dish, which is built up during the evaporation process, coincides with the location where dewetting predominantly starts. This hypothesis could be supported by measurements of the CuCl2 coverage of the Petri dish. During the evaporation the height of the meniscus at the rim of the Petri dish recedes in favor of the central Petri dish area. This could not be explained by the above mentioned hypothesis.

3.
J Sci Food Agric ; 95(1): 53-8, 2015 Jan.
Article in English | MEDLINE | ID: mdl-25044434

ABSTRACT

BACKGROUND: There is a need for authentication tools in order to verify the existing certification system. Recently, markers for analytical authentication of organic products were evaluated. Herein, crystallization with additives was described as an interesting fingerprint approach which needs further evidence, based on a standardized method and well-documented sample origin. RESULTS: The fingerprint of wheat cultivars from a controlled field trial is generated from structure analysis variables of crystal patterns. Method performance was tested on factors such as crystallization chamber, day of experiment and region of interest of the patterns. Two different organic treatments and two different treatments of the non-organic regime can be grouped together in each of three consecutive seasons. When the k-nearest-neighbor classification method was applied, approximately 84% of Runal samples and 95% of Titlis samples were classified correctly into organic and non-organic origin using cross-validation. CONCLUSION: Crystallization with additive offers an interesting complementary fingerprint method for organic wheat samples. When the method is applied to winter wheat from the DOK trial, organic and non-organic treated samples can be differentiated significantly based on pattern recognition. Therefore crystallization with additives seems to be a promising tool in organic wheat authentication.


Subject(s)
Food, Organic/classification , Triticum/chemistry , Triticum/classification , Crystallization , Organic Agriculture , Reproducibility of Results , Seasons , Seeds/chemistry
4.
J Colloid Interface Sci ; 344(2): 556-62, 2010 Apr 15.
Article in English | MEDLINE | ID: mdl-20116068

ABSTRACT

The overall structure of the crystallization results of dihydrate cupric chloride with additives in a petri dish is affected by the duration between the beginning of the evaporation and the start of the crystallization. Experiments done with polyvinylpyrrolidone and freeze-dried carrot as additive are compared with those of the additive free case. The dependency of dewetting on the dihydrate cupric chloride amount is discussed in terms of depletion of the solution and the surface tension properties of the system. The possible influence of the depletion is depending on the moment the crystallization starts. This is defined by the size of the evaporated area on the dish.


Subject(s)
Copper/chemistry , Daucus carota/chemistry , Povidone/chemistry , Water/chemistry , Crystallization , Particle Size , Solutions , Surface Properties , Volatilization
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