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1.
Knee ; 36: 27-32, 2022 Jun.
Article in English | MEDLINE | ID: mdl-35447466

ABSTRACT

BACKGROUND: Femoral component fracture is a rare complication of total knee arthroplasty (TKA). CASE: We report a case of oxidized zirconium (Oxinium) femoral component fracture after total knee arthroplasty. The fracture site was the junction of the central and medial flanges. The patellar component and polyethylene insert had delamination at the contact point of the fracture line, and the tibial tray had loosening at the medial side. There was no cement adherence at the component fracture site, suggesting that debonding had occurred at the cement-implant interface in this area. Examination with a scanning electron microscope revealed beach marks, which are characteristic findings of metal fatigue. CONCLUSION: We considered that the cause of femoral component fracture was a fatigue fracture due to poor fixation of the component to the bone caused by poor osteotomy technique or poor cementing technique. To our knowledge, this is the first case of Oxinium femoral component fracture.


Subject(s)
Arthroplasty, Replacement, Knee , Femoral Fractures , Knee Prosthesis , Arthroplasty, Replacement, Knee/adverse effects , Arthroplasty, Replacement, Knee/methods , Humans , Knee Prosthesis/adverse effects , Polyethylene , Prosthesis Failure , Zirconium
2.
Chem Commun (Camb) ; (36): 3794-6, 2006 Sep 28.
Article in English | MEDLINE | ID: mdl-16969460

ABSTRACT

Selective monoiodination of aromatic compounds such as dimethoxybenzene has been successfully achieved with I+, which is generated by anodic oxidation of I2 in acetonitrile, using micromixing.


Subject(s)
Electrochemistry , Hydrocarbons, Aromatic/chemistry , Hydrocarbons, Iodinated/chemical synthesis , Iodine/chemistry , Microfluidics , Acetonitriles/chemistry , Anisoles/chemistry , Electrodes , Mass Spectrometry , Oxidation-Reduction
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