1.
Chem Asian J
; 8(6): 1115-9, 2013 Jun.
Article
in English
| MEDLINE
| ID: mdl-23512755
ABSTRACT
Catecholate catwalk: Monomeric manganese(III) catecholato and manganese(II) semiquinonato complexes as the substrate-binding model of catechol dioxygenase have been synthesized and structurally characterized. The semiquinonato complex reacted with molecular oxygen to give ring-cleaved products and benzoquinone in the catalytic condition.