Water quality evaluation and ecological-health risk assessment on trace elements in surface water of the northeastern Qinghai-Tibet Plateau.

The Qinghai-Tibet Plateau is a unique area with water sources for approximately 40 % of the population in the world. Water resources and water quality are closely associated with ecological security and human health. Fifty-one trace elements in surface water samples (n = 40) were measured, and water quality, health and ecological risks were assessed. Trace elements showed significant variations in different surface water bodies in the study area. Concentrations of minor elements were relatively high in saline and salt lakes while those of REEs varied from 0.05 to 33.62 µg/L with an average value of 3.80 µg/L. The Nemerow pollution index (NP) values of trace elements ranged from 0.08 to 3.48, with an average value of 0.36 in rivers, fresh lakes and reservoir water samples; The heavy metal pollution index (HPI) values ranged from 3.70 to 21.18, indicating that most samples were within the critical limit; The heavy metal evaluation index (HEI) values and degree of contamination (DC) values indicated a free pollution status. The water quality index (WQI) values showed that 96 % of the samples belonged to excellent status in rivers, fresh lakes and reservoir water samples. More attention should be given to the Cr, Zn and Hg in the study area according to potential ecological risk assessment. Hazard quotients for residential children in 30 sites exceed 1.0 with maximal value of 10.97, suggesting the high non-carcinogenic risks for children in the study area. U, Zr and Cr for the ingestion pathway, Cr and U for the dermal pathway were primary contributors to the total health risk. Carcinogenic risk values of trace elements for residential and recreational receptors were in the range of 3.20 × 10-5-7.38 × 10-3 and 8.62 × 10-6-3.63 × 10-3, respectively. The carcinogenic risk values of Cr in surface water were higher than the target risk of 1 × 10-4, while the carcinogenic risk values of As were below the target risk. The results of this study provided information on trace elements for human health protection and water management in the northeastern Qinghai-Tibet Plateau.

Distribution of Black Carbon in Topsoils of the Northeastern Qinghai-Tibet Plateau Under Natural and Anthropogenic Influences.

Black carbon (BC), ubiquitous in soils, plays an important role in global carbon cycles, the radiative heat balance of the Earth, pollutant fate, emissions of greenhouse gas, soil fertility, soil microbial community, and ecosystem stability. However, information on BC in topsoils of the northeastern Qinghai-Tibet Plateau is limited. Therefore, this study performed field sampling and analyzed contents of total BC and soot BC in topsoils. The results indicated that the contents of total BC in all soil samples ranged from 0.504 to 74.381 g kg-1 with an average value of 5.152 g kg-1, whereas those of soot BC were in the range of 0.400-15.200 g kg-1 with a mean value of 1.719 g kg-1. Contents of BC were significantly correlated with those of total carbon and total organic carbon. Soil types affected the distribution of soil BC. The contents of total BC in the loam soils were larger than those in the clay soils, whereas soot BC was more easily enriched in the clay soils. Total BC was negatively correlated with Ca, and soot BC was negatively correlated with Ti. The contents of soil BC in functional areas, such as agricultural and pastoral areas, industrial areas, and mining areas, were significantly higher than those in other areas, illustrating that anthropogenic activities drastically affected the distribution of soil BC. This study exhibits the fundamental information on soil BC in the northeastern Qinghai-Tibet Plateau to provide important knowledge on global soil carbon sink.

Adsorptive Removal of Tetracyclines and Fluoroquinolones Using Yak Dung Biochar.

This study investigated the adsorptive removal of target fluoroquinolones and tetracyclines by biochar made by yak dung collected from the Qinghai-Tibet Plateau. Yak dung biochar pyrolyzed at 700 °C possessed surface area of 198.745 m2 g-1 and multiple functional groups. Effects of different factors including biochar dosage, pH, temperature, and initial concentration on adsorption of antibiotics were discussed. The biochar dosage of 1 g L-1 was preferable for adsorptive removal of antibiotics. Adsorption of target antibiotics did not show pH-dependent features. Adsorption capacities of fluoroquinolones and tetracyclines positively increased with temperature and initial concentration. Pseudo-second order model and the Freundlich model better fitted the experimental kinetic and isotherm data, respectively. Yak dung biochar provides a new idea on resource utilization of solid wastes and pollution control in the Qinghai-Tibet Plateau.

Distribution, pollution, bioaccumulation, and ecological risks of trace elements in soils of the northeastern Qinghai-Tibet Plateau.

Environmental quality of the northeastern Qinghai-Tibet Plateau has attracted more attention due to increasing anthropogenic disturbance. Therefore, this study investigated the distribution, pollution, ecological risks, and bioaccumulation of 12 target heavy metals and 16 rare earth elements (REEs) in soils of this area. The average concentrations of target trace elements in soils ranged from 0.16 (Hg) to 500.46 (Cr) mg/kg. Pb caused more serious pollution than the other elements based on geo-accumulation index evaluation. Hg exhibited the strongest enrichment feature with the average enrichment factor of 8.41. Compare with modified contamination degree and pollution load index, Nemerow pollution index method obtained the most serious evaluation results that 45.67% and 16.54% of sampling sites possessed high and moderate pollution. Evaluation results of potential ecological risk index showed that trace elements in soils posed very high and considerable ecological risks in 34.65% and 7.09% of sampling sites, respectively. Mining area was the region with the most serious pollution and ecological risks. Average bioaccumulation factor (BCF) values of target trace elements ranged from 0.05 (REEs) to 2.67 (Cr). Cr was the element that was easier to bio-accumulate in plants of the study area than the other target elements. It is in urgent need to take effective measures for controlling current pollution and potential ecological risks of trace elements in soils of the northeastern Qinghai-Tibet Plateau.

Distribution and health risks of aerosol black carbon in a representative city of the Qinghai-Tibet Plateau.

Although aerosol black carbon (BC) exerts strong influences on human health, research on potential health risks of aerosol BC around the Qinghai-Tibet Plateau is very limited. This is the very first study to investigate the distribution of aerosol BC in a typical city of the Qinghai-Tibet Plateau and the resulting health risks. The results showed that the maximal real-time (5-min monitoring interval) concentration of aerosol BC was 22.34 µg/m3, much higher than day- and week-averaged concentrations which were in the range of 1.28-6.15 and 1.93-4.63 µg/m3, respectively. The health risks were evaluated using four different health endpoints including low birth weight (LBW), percentage lung function decrement of school-aged children (PLFD), cardiovascular mortality (CM), and lung cancer (LC). The highest risks of LBW, PLFD, CM, and LC had reached 69.5, 184.4, 67.4, and 31.8 numbers of equivalent passively smoked cigarettes (PSC), respectively. The concentrations and health risks of aerosol BC in the study area are at a middle level among the global cities/regions. In comparison, the cities of the Qinghai-Tibet Plateau are experiencing high potential health risks resulting from aerosol BC to need more effective prevention and control of air pollution.

Pollution, ecological-health risks, and sources of heavy metals in soil of the northeastern Qinghai-Tibet Plateau.

The Qinghai-Tibet Plateau, especially the northeastern region, is not a pure land any more due to recently increasing anthropogenic activities. This study collected soil samples from 70 sites of the northeastern Qinghai-Tibet Plateau to evaluate pollution, ecological-health risks, and possible pollution sources of heavy metals. The concentrations of heavy metals in soil were relatively high. Values of geo-accumulation index exhibited that Hg pollution was the most serious meanwhile Hg possessed the strongest enrichment feature based on enrichment factor values. The modified degrees of contamination showed that about 54.3% and 17.1% of sampling sites were at moderate and high contamination degree while pollution load indexes illustrated that 72.9% and 27.1% of sampling sites possessed moderate and high contamination level, respectively. Ecological risk indexes of heavy metals in soil ranged from 234.6 to 3759.0, suggesting that most of sites were under considerable/very high risks. Cancer risks for adults and children were determined as high and high-very high levels while non-cancer risks for children were high although those for adults were low. Industrial source contributed to the main fraction of ecological and health risks. Summarily speaking, heavy metals in soil of the study area has caused significantly serious pollution and exerted high potential ecological and health risks, especially for children who are more susceptible to hurt from pollutants. Therefore, more efficient and strict pollution control and management in study area should be put out as soon as possible.

An overview on the organic pollution around the Qinghai-Tibet plateau: The thought-provoking situation.

The Qinghai-Tibet Plateau plays an important role in the ecological safety and human health of the surroundings due to its unique geographical position and function. Therefore, it is necessary to study the pollution status and potential risk in this area. This study summarizes the distribution of different organic pollutants in biota and environmental media of the Qinghai-Tibet Plateau. Moreover, it also pays attention to the potential health risks of these organic pollutants. Organochlorine pesticides (OCPs), polycyclic aromatic hydrocarbons (PAHs), polychlorinated biphenyls (PCBs), and polybrominated diphenyl ethers (PBDEs) were the most frequently detected in different matrices. In general, the carcinogenic risks of organic pollutants were ranked in the very-low to moderate range for both children and adults. The carcinogenic risks of organic pollutants in fish, food, and water for children were 1-2 times higher than those for adults, while risks of organic pollutants in soil/sediment and in air for children were generally 10.6-16.5 and 2.6-2.8 times higher than those for adults, respectively. The maximal hazard quotient for non-carcinogenic risk was 0.95 (potential risk for children posed by organic pollutants in yak milk of Ruoergai), almost reaching an unacceptable level. Therefore, the potential health risks could not be neglected, especially for children who were more likely to be affected by the pollutants.