Toward direct measurement of atmospheric nucleation.

Atmospheric aerosol formation is known to occur almost all over the world, and the importance of these particles to climate and air quality has been recognized. Although almost all of the processes driving aerosol formation take place below a particle diameter of 3 nanometers, observations cover only larger particles. We introduce an instrumental setup to measure atmospheric concentrations of both neutral and charged nanometer-sized clusters. By applying the instruments in the field, we come to three important conclusions: (i) A pool of numerous neutral clusters in the sub-3 nanometer size range is continuously present; (ii) the processes initiating atmospheric aerosol formation start from particle sizes of approximately 1.5 nanometers; and (iii) neutral nucleation dominates over the ion-induced mechanism, at least in boreal forest conditions.

Relationship between different size classes of particulate matter and meteorology in three European cities.

Evidence on the correlation between particle mass and (ultrafine) particle number concentrations is limited. Winter- and spring-time measurements of urban background air pollution were performed in Amsterdam (The Netherlands), Erfurt (Germany) and Helsinki (Finland), within the framework of the EU funded ULTRA study. Daily average concentrations of ambient particulate matter with a 50% cut off of 2.5 microm (PM2.5), total particle number concentrations and particle number concentrations in different size classes were collected at fixed monitoring sites. The aim of this paper is to assess differences in particle concentrations in several size classes across cities, the correlation between different particle fractions and to assess the differential impact of meteorological factors on their concentrations. The medians of ultrafine particle number concentrations were similar across the three cities (range 15.1 x 10(3)-18.3 x 10(3) counts cm(-3)). Within the ultrafine particle fraction, the sub fraction (10-30 nm) made a higher contribution to particle number concentrations in Erfurt than in Helsinki and Amsterdam. Larger differences across the cities were found for PM2.5(range 11-17 microg m(-3)). PM2.5 and ultrafine particle concentrations were weakly (Amsterdam, Helsinki) to moderately (Erfurt) correlated. The inconsistent correlation for PM2.5 and ultrafine particle concentrations between the three cities was partly explained by the larger impact of more local sources from the city on ultrafine particle concentrations than on PM2.5, suggesting that the upwind or downwind location of the measuring site in regard to potential particle sources has to be considered. Also, relationship with wind direction and meteorological data differed, suggesting that particle number and particle mass are two separate indicators of airborne particulate matter. Both decreased with increasing wind speed, but ultrafine particle number counts consistently decreased with increasing relative humidity, whereas PM2.5 increased with increasing barometric pressure. Within the ultrafine particle mode, nucleation mode (10-30 nm) and Aitken mode (30-100 nm) had distinctly different relationships with accumulation mode particles and weather conditions. Since the composition of these particle fractions also differs, it is of interest to test in future epidemiological studies whether they have different health effects.

Resuspended dust episodes as an urban air-quality problem in subarctic regions.

OBJECTIVES: This paper describes the resuspension of road dust in an urban subarctic environment and focuses especially on the effect of wind speed on the formation of resuspended dust episodes. METHODS: The study was conducted in Kuopio, Finland, in the spring of 1995. There were 36 daily measurements of mass concentrations of fine particulate matter (PM2.5), thoracic particulate matter (PM10), total suspended particulate matter, black carbon and carbon monoxide; size-segregated number concentrations of particles (diameter range 0.01-10 microm); and meteorological parameters. Total elemental compositions of PM2.5 and PM10 samples were analyzed with inductively coupled plasma mass spectrometry. RESULTS: The mass and number concentrations of particles in all the size ranges and the concentrations of soil-derived (iron) and combustion-derived (vanadium and lead) elements in the PM2.5 and PM10 increased during the dust episodes. The daily average wind speed dually affected the episodes. The pollutant concentrations increased at wind speeds of <4 m/s and >5 m/s. The former was related to inversion-type conditions characterized by low wind speeds, while the latter was likely to be due to wind-blown resuspended dust. Resuspended lead accounted for an average of 27% of the total lead, and resuspended vanadium for 46% of the total vanadium in PM2.5. CONCLUSIONS: Resuspended dust episodes were related to both low and high wind speeds, and the relationship suggests that factors other than wind speed, such as turbulence induced by traffic, affect the emergence of such episodes. The contribution of elevated levels of crustal material and toxic metals in resuspended PM2.5 to human adverse health effects should be investigated.