A compact von Hámos spectrometer for parallel X-ray Raman scattering and X-ray emission spectroscopy at ID20 of the European Synchrotron Radiation Facility.

A compact spectrometer for medium-resolution resonant and non-resonant X-ray emission spectroscopy in von Hámos geometry is described. The main motivation for the design and construction of the spectrometer is to allow for acquisition of non-resonant X-ray emission spectra while measuring non-resonant X-ray Raman scattering spectra at beamline ID20 of the European Synchrotron Radiation Facility. Technical details are provided and the performance and possible use of the spectrometer are demonstrated by presenting results of several X-ray spectroscopic methods on various compounds.

Improving the spatial and statistical accuracy in X-ray Raman scattering based direct tomography.

An algorithm to simultaneously increase the spatial and statistical accuracy of X-ray Raman scattering (XRS) based tomographic images is presented. Tomography that utilizes XRS spectroscopy signals as a contrast for the images is a new and promising tool for investigating local atomic structure and chemistry in heterogeneous samples. The algorithm enables the spatial resolution to be increased based on a deconvolution of the optical response function of the spectrometer and, most importantly, it allows for the combination of data collected from multiple analyzers and thus enhances the statistical accuracy of the measured images.

Direct tomography imaging for inelastic X-ray scattering experiments at high pressure.

A method to separate the non-resonant inelastic X-ray scattering signal of a micro-metric sample contained inside a diamond anvil cell (DAC) from the signal originating from the high-pressure sample environment is described. Especially for high-pressure experiments, the parasitic signal originating from the diamond anvils, the gasket and/or the pressure medium can easily obscure the sample signal or even render the experiment impossible. Another severe complication for high-pressure non-resonant inelastic X-ray measurements, such as X-ray Raman scattering spectroscopy, can be the proximity of the desired sample edge energy to an absorption edge energy of elements constituting the DAC. It is shown that recording the scattered signal in a spatially resolved manner allows these problems to be overcome by separating the sample signal from the spurious scattering of the DAC without constraints on the solid angle of detection. Furthermore, simple machine learning algorithms facilitate finding the corresponding detector pixels that record the sample signal. The outlined experimental technique and data analysis approach are demonstrated by presenting spectra of the Si L2,3-edge and O K-edge of compressed α-quartz. The spectra are of unprecedented quality and both the O K-edge and the Si L2,3-edge clearly show the existence of a pressure-induced phase transition between 10 and 24 GPa.

Planning, performing and analyzing X-ray Raman scattering experiments.

A compilation of procedures for planning and performing X-ray Raman scattering (XRS) experiments and analyzing data obtained from them is presented. In particular, it is demonstrated how to predict the overall shape of the spectra, estimate detection limits for dilute samples, and how to normalize the recorded spectra to absolute units. In addition, methods for processing data from multiple-crystal XRS spectrometers with imaging capability are presented, including a super-resolution method that can be used for direct tomography using XRS spectra as the contrast. An open-source software package with these procedures implemented is also made available.

Photoinduced melting of antiferromagnetic order in La(0.5)Sr(1.5)MnO4 measured using ultrafast resonant soft x-ray diffraction.

We used ultrafast resonant soft x-ray diffraction to probe the picosecond dynamics of spin and orbital order in La(0.5)Sr(1.5)MnO(4) after photoexcitation with a femtosecond pulse of 1.5 eV radiation. Complete melting of antiferromagnetic spin order is evidenced by the disappearance of a (1/4,1/4,1/2) diffraction peak. On the other hand, the (1/4,1/4,0) diffraction peak, reflecting orbital order, is only partially reduced. We interpret the results as evidence of destabilization in the short-range exchange pattern with no significant relaxation of the long-range Jahn-Teller distortions. Cluster calculations are used to analyze different possible magnetically ordered states in the long-lived metastable phase. Nonthermal coupling between light and magnetism emerges as a primary aspect of photoinduced phase transitions in manganites.

Orbital order at Mn and O sites and absence of Zener polaron formation in manganites.

We report the doping dependence of the ground state of A-site ordered manganites below and above half doping. Energy and polarization dependence of the orbital reflection, taken by resonant soft-x-ray powder diffraction, at both Mn L(2,3) and O K edges, provides direct evidence for orbital order at Mn(3+) and oxygen sites and absence of Zener polaron formation. For x > or = 0.2 anomalous melting of the orbital order is observed, which is coupled neither to magnetic ordering nor to a structural transition, indicating a two-dimensional character of the interactions.

Unraveling orbital ordering in La0.5Sr1.5MnO4.

Orbital ordering (OO) in the layered perovskite La0.5Sr1.5MnO4 has been investigated using the enhanced sensitivity of soft x-ray resonant diffraction at the Mn L edges. The energy dependence of an OO diffraction peak over the L(2,3) edges is compared to ligand-field calculations allowing a distinction between the influences of Jahn-Teller distortions and spin correlations. The energy dependence of the diffraction peak at the Mn L1 edge is remarkably different from that observed at the Mn K edge.

Anomalous dispersion of longitudinal optical phonons in Nd(1.86)Ce(0.14)CuO(4+delta) determined by inelastic x-ray scattering.

The phonon dispersions of Nd(1.86)Ce(0.14)CuO(4+delta) along the [xi,0,0] direction have been determined by inelastic x-ray scattering. Compared to the undoped parent compound, the two highest longitudinal phonon branches, associated with the Cu-O bond stretching and out-of-plane oxygen vibration, are shifted to lower energies. Moreover, an anomalous softening of the bond-stretching band is observed at about q = (0.2,0,0). These signatures provide evidence for strong electron-phonon coupling in this electron-doped high-temperature superconductor.

Estudio de la fuerza muscular de 393 carteros urbanos argentinos / Cross-sectional study of handgrip strength in 393 Argentinean postmen

La fuerza muscular es un importante factor fisiológico determinante de la eficiencia laboral. El objetivo de este estudio fue establecer el efecto del avance de la edad sobre la máxima fuerza muscular y su relación con los cambios en el peso corporal (IMC) y en la adiposidad en carteros argentinos que clasifican y distribuyen la correspondencia en áreas urbanas. De la población de carteros del área metropolitana del Correo Argentino se seleccionaron al azar 393 (edad: 19-64 años). En cada sujeto se midió la estatura y el peso corporal, el espesor de los pliegues cutáneos de tríceps, cresta ilíaca y subescapular, las circunferencias de brazo y de cintura y la máxima fuerza isométrica de los músculos presentes de la mano. Los datos presentados en este estudio muestran que la máxima fuerza muscular decrece significativamente con la edad, aunque el deterioro es significativo a partir de la quinta década de la vida. A diferencia de lo que ha sido reportado por otros autores, en este estudio dicha disminución no se acentúa entre los 45 y los 64 años. Este hecho se atribuye al entrenamiento que significa la diaria actividad laboral del cartero (AU)

Numerical and experimental study of grating efficiency for synchrotron monochromators.

The development of third-generation synchrotron sources has stimulated efforts toward high-resolution monochromators. A good knowledge of grating efficiency is needed to achieve an optimal compromise between resolution and photon flux. Because simple geometric models fail to describe correctly the gratings properties in the UVtosoft-X-ray range, we have developed a simulation software based on differential theory. A simplified R-matrix propagation algorithm assures the numerical stability of the code for deep gratings. Our numerical results are compared with previous research on deep gratings. Experimental and numerical studies have been performed on some test cases at a synchrotron source. Very good agreement between numerical prediction and measurement has been found.

Optimization strategies for XUV monochromators.

The techniques of monochromator optimization are reviewed, and it is shown that until recently only a few of the available parameters were used at the same time. Efficient optimization can be performed numerically. The computation method developed at LURE is explained and an example is given. Extension and development of the method are outlined.