Functionalizing aromatic compounds with optical cycling centres.

Molecular design principles provide guidelines for augmenting a molecule with a smaller group of atoms to realize a desired property or function. We demonstrate that these concepts can be used to create an optical cycling centre, the Ca(I)-O unit, that can be attached to a number of aromatic ligands, enabling the scattering of many photons from the resulting molecules without changing the molecular vibrational state. Such capability plays a central role in quantum state preparation and measurement, as well as laser cooling and trapping, and is therefore a prerequisite for many quantum science and technology applications. We provide further molecular design principles that indicate the ability to optimize and expand this work to an even broader class of molecules. This represents a great step towards a quantum functional group, which may serve as a generic qubit moiety that can be attached to a wide range of molecular structures and surfaces.

Pathway toward Optical Cycling and Laser Cooling of Functionalized Arenes.

Rapid and repeated photon cycling has enabled precision metrology and the development of quantum information systems using atoms and simple molecules. Extending optical cycling to structurally complex molecules would provide new capabilities in these areas, as well as in ultracold chemistry. Increased molecular complexity, however, makes realizing closed optical transitions more difficult. Building on already established strong optical cycling of diatomic, linear triatomic, and symmetric top molecules, recent work has pointed the way to cycling of larger molecules, including phenoxides. The paradigm for these systems is an optical cycling center bonded to a molecular ligand. Theory has suggested that cycling may be extended to even larger ligands, like naphthalene, pyrene, and coronene. Herein, we study optical excitation and fluorescent vibrational branching of CaO-[Formula: see text], SrO-[Formula: see text], and CaO-[Formula: see text] and find only weak decay to excited vibrational states, indicating a promising path to full quantum control and laser cooling of large arene-based molecules.

Magneto-optical trapping and sub-Doppler cooling of a polyatomic molecule.

Laser cooling and trapping1,2, and magneto-optical trapping methods in particular2, have enabled groundbreaking advances in science, including Bose-Einstein condensation3-5, quantum computation with neutral atoms6,7 and high-precision optical clocks8. Recently, magneto-optical traps (MOTs) of diatomic molecules have been demonstrated9-12, providing access to research in quantum simulation13 and searches for physics beyond the standard model14. Compared with diatomic molecules, polyatomic molecules have distinct rotational and vibrational degrees of freedom that promise a variety of transformational possibilities. For example, ultracold polyatomic molecules would be uniquely suited to applications in quantum computation and simulation15-17, ultracold collisions18, quantum chemistry19 and beyond-the-standard-model searches20,21. However, the complexity of these molecules has so far precluded the realization of MOTs for polyatomic species. Here we demonstrate magneto-optical trapping of a polyatomic molecule, calcium monohydroxide (CaOH). After trapping, the molecules are laser cooled in a blue-detuned optical molasses to a temperature of 110 µK, which is below the Doppler cooling limit. The temperatures and densities achieved here make CaOH a viable candidate for a wide variety of quantum science applications, including quantum simulation and computation using optical tweezer arrays15,17,22,23. This work also suggests that laser cooling and magneto-optical trapping of many other polyatomic species24-27 will be both feasible and practical.

Direct laser cooling of a symmetric top molecule.

Ultracold polyatomic molecules have potentially wide-ranging applications in quantum simulation and computation, particle physics, and quantum chemistry. For atoms and small molecules, direct laser cooling has proven to be a powerful tool for quantum science in the ultracold regime. However, the feasibility of laser-cooling larger, nonlinear polyatomic molecules has remained unknown because of their complex structure. We laser-cooled the symmetric top molecule calcium monomethoxide (CaOCH3), reducing the temperature of ~104 molecules from 22 ± 1 millikelvin to 1.8 ± 0.7 millikelvin in one dimension and state-selectively cooling two nuclear spin isomers. These results demonstrate that the use of proper ro-vibronic transitions enables laser cooling of nonlinear molecules, thereby opening a path to efficient cooling of chiral molecules and, eventually, optical tweezer arrays of complex polyatomic species.

Assessment and mitigation of aerosol airborne SARS-CoV-2 transmission in laboratory and office environments.

Bioaerosols are known to be an important transmission pathway for SARS-CoV-2. We report a framework for estimating the risk of transmitting SARS-CoV-2 via aerosols in laboratory and office settings, based on an exponential dose-response model and analysis of air flow and purification in typical heating, ventilation, and air conditioning (HVAC) systems. High-circulation HVAC systems with high-efficiency particulate air (HEPA) filtration dramatically reduce exposure to the virus in indoor settings, and surgical masks or N95 respirators further reduce exposure. As an example of our risk assessment model, we consider the precautions needed for a typical experimental physical science group to maintain a low risk of transmission over six months of operation. We recommend that, for environments where fewer than five individuals significantly overlap, work spaces should remain vacant for between one (high-circulation HVAC with HEPA filtration) to six (low-circulation HVAC with no filtration) air exchange times before a new worker enters in order to maintain no more than 1% chance of infection over six months of operation in the workplace. Our model is readily applied to similar settings that are not explicitly given here. We also provide a framework for evaluating infection mitigation through ventilation in multiple occupancy spaces.

1D Magneto-Optical Trap of Polyatomic Molecules.

We demonstrate a 1D magneto-optical trap of the polar free radical calcium monohydroxide (CaOH). A quasiclosed cycling transition is established to scatter ∼10^{3} photons per molecule, predominantly limited by interaction time. This enables radiative laser cooling of CaOH while compressing the molecular beam, leading to a significant increase in on axis beam brightness and reduction in temperature from 8.4 to 1.4 mK.

Bad metallic transport in a cold atom Fermi-Hubbard system.

Strong interactions in many-body quantum systems complicate the interpretation of charge transport in such materials. To shed light on this problem, we study transport in a clean quantum system: ultracold lithium-6 in a two-dimensional optical lattice, a testing ground for strong interaction physics in the Fermi-Hubbard model. We determine the diffusion constant by measuring the relaxation of an imposed density modulation and modeling its decay hydrodynamically. The diffusion constant is converted to a resistivity by using the Nernst-Einstein relation. That resistivity exhibits a linear temperature dependence and shows no evidence of saturation, two characteristic signatures of a bad metal. The techniques we developed in this study may be applied to measurements of other transport quantities, including the optical conductivity and thermopower.

Spin-imbalance in a 2D Fermi-Hubbard system.

The interplay of strong interactions and magnetic fields gives rise to unusual forms of superconductivity and magnetism in quantum many-body systems. Here, we present an experimental study of the two-dimensional Fermi-Hubbard model-a paradigm for strongly correlated fermions on a lattice-in the presence of a Zeeman field and varying doping. Using site-resolved measurements, we revealed anisotropic antiferromagnetic correlations, a precursor to long-range canted order. We observed nonmonotonic behavior of the local polarization with doping for strong interactions, which we attribute to the evolution from an antiferromagnetic insulator to a metallic phase. Our results pave the way to experimentally mapping the low-temperature phase diagram of the Fermi-Hubbard model as a function of both doping and spin polarization, for which many open questions remain.

Phase Separation and Pair Condensation in a Spin-Imbalanced 2D Fermi Gas.

We study a two-component quasi-two-dimensional Fermi gas with imbalanced spin populations. We probe the gas at different interaction strengths and polarizations by measuring the density of each spin component in the trap and the pair momentum distribution after time of flight. For a wide range of experimental parameters, we observe in-trap phase separation characterized by the appearance of a spin-balanced core surrounded by a polarized gas. Our momentum space measurements indicate pair condensation in the imbalanced gas even for large polarizations where phase separation vanishes, pointing to the presence of a polarized pair condensate. Our observation of zero momentum pair condensates in 2D spin-imbalanced gases opens the way to explorations of more exotic superfluid phases that occupy a large part of the phase diagram in lower dimensions.