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Direct aldol reactions catalyzed by intramolecularly folded prolinamide dendrons: dendrimer effects on stereoselectivity.
Mitsui, Kazuhiko; Hyatt, Sarah A; Turner, Daniel A; Hadad, Christopher M; Parquette, Jon R.
Chem Commun (Camb) ; (22): 3261-3, 2009 Jun 14.
Article in English | MEDLINE | ID: mdl-19587933

ABSTRACT

Dendritic effects on both the enantioselectivity and diastereoselectivity of the direct aldol reaction were observed for pyridine-2,6-dicarboxamide dendrons terminated with L-prolinamides.


Subject(s)
Aldehydes/chemistry , Dendrimers/chemistry , Proline/analogs & derivatives , Catalysis , Crystallography, X-Ray , Proline/chemistry , Stereoisomerism , Substrate Specificity
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