ABSTRACT
In this study, a facile and scalable method for synthesizing MoSe2 nanomaterial via a sonication-assisted liquid-phase exfoliation method is proposed. This study shows the successful synthesis of few-layered MoSe2 in various solvents including DI water, ethanol, N-Methyl-2-pyrrolidone (NMP), Dimethylformamide (DMF) and Dimethylsulfoxide (DMSO). The exfoliated nanosheets have remarkably different properties than bulk MoSe2 which were studied using Field emission scanning electron microscopy, Fourier-transform infrared spectroscopy, X-ray diffraction and UV-Vis spectroscopy to investigate their morphology, functional groups, structure and optical properties, respectively. The mean values of the number of layers from an optical extinction spectrum based on the effect of edge and quantum confinement were also calculated. Moreover, the exfoliated material using this method has potential application in energy storage as demonstrated by the electrochemical performance of the bulk and exfoliated materials.â¢Successful synthesis of the few-layer MoSe2 from bulk MoSe2 using liquid phase exfoliation method in various solventsâ¢The investigation of the effect of solvent on the number of layers and optical properties of MoSe2.
ABSTRACT
COVID-19-led antibiotic waste generated from hospitals and health centres may cause serious health issues and significantly impact the environment. In the coming decades, antibiotic resistance will be one of the most significant threats to global human health. Photocatalytic water remediation is an effective and promising environmental solution that can be utilized to address this issue, to convert antibiotic waste into non-toxic products by utilizing renewable and abundant solar energy. In the present study, a novel nanocomposite of zeolitic imidazolate frameworks (ZIF-8) and molybdenum diselenide (MoSe2) was efficiently synthesized by the solvothermal method for the complete degradation of the antibiotics and textile waste from water. The morphology, crystallinity and band gap of the samples were characterized by field emission scanning electron microscopy (FESEM), X-ray diffraction (XRD) and UV-visible spectroscopy. Fourier transform infrared spectroscopy (FTIR) and X-ray photoelectron spectroscopy (XPS) provide the binding information of the sample. The photocatalytic activity was tested for degradation of the antibiotics (tetracycline hydrochloride (TC) and metronidazole (MNZ)) used in COVID-19 treatment and textile dye (malachite green). Time-resolved photoluminescence spectroscopy confirmed the enhanced charge separation in the MoSe2@ZIF-8 nanocomposite with an average lifetime of 4.72 ns as compared to pristine samples. The nanocomposite showed ~ 100% removal efficiency with rate constants of 63 × 10-3, 49 × 10-3 and 42 × 10-3 min-1 for TC, MNZ and malachite green, respectively. The photocatalytic degradation of TC was carried out under different pH conditions (4, 7 and 9), and the degradation mechanism was explained on the basis of zeta potential measurements and active species trapping experiment. The by-products of the photocatalytic treatment of TC antibiotics were tested using liquid chromatography-mass spectroscopy (LC-MS), and they were found to be non-toxic for aquatic and human life. The regeneration property of the nanocomposite was confirmed by FESEM with regeneration efficiency of 88.7% in the 4th cycle. Thus, MoSe2@ZIF-8-based photocatalysts have potential application in water remediation, especially in making the antibiotic waste less toxic.
Subject(s)
COVID-19 , Nanocomposites , Zeolites , Humans , Anti-Bacterial Agents , Wastewater , COVID-19 Drug Treatment , Nanocomposites/chemistry , Metronidazole , Water , CatalysisABSTRACT
In this paper, we are reporting a simple hydrothermal technique for preparation of MoSe2 nanostructures (nanourchins and nanosheets) using selenium and sodium molybdate as precursors. Samples are characterized by field emission scanning electron microscopy (FESEM), X-ray diffraction (XRD), Raman spectroscopy, UV-Vis spectroscopy, Brunauer-Emmett-Teller (BET), and X-ray photoelectron spectroscopy (XPS). The FESEM revealed that the morphology of materials was varying significantly by changing pH value during synthesis. Photocatalytic degradation of anionic dye (MO), cationic dye (MB), and reduction of Cr(VI) into Cr(III) were performed. Nanosheets and nanourchins showed higher photocatalytic activity, enhanced photocatalytic degradation efficiency is correlated with the higher â¢OH radical concentration, crystallinity of material, and large surface area as evident through XPS, XRD, and BET, respectively. Photocatalysis mechanism along with role of reactive species (â¢OH and holes) were explained using trapping experiments. Identification of degraded products was carried out using high-performance liquid chromatography (HPLC). Reaction kinetics and reusability of materials were also studied; wherein, it was observed that the materials have reusable properties.
