Potential Applications of Nickel-Based Metal-Organic Frameworks and their Derivatives.

Metal-Organic Frameworks (MOFs), a novel class of porous extended crystalline structures, are favored in different fields of heterogeneous catalysis, CO2 separation and conversion, and energy storage (supercapacitors) due to their convenience of synthesis, structural tailor-ability, tunable pore size, high porosity, large specific surface area, devisable structures, and adjustable compositions. Nickel (Ni) is a ubiquitous element extensively applied in various fields of catalysis and energy storage due to its low cost, high abundance, thermal and chemical stability, and environmentally benign nature. Ni-based MOFs and their derivatives provide us with the opportunity to modify different properties of the Ni center to improve their potential as heterogeneous catalysts or energy storage materials. The recent achievements of Ni-MOFs and their derivatives as catalysts, membrane materials for CO2 separation and conversion, electrode materials and their respective performance have been discussed in this review.

Bioinspired Heterocyclic Compounds as Corrosion Inhibitors: A Comprehensive Review.

Corrosion is a phenomenon that devastatingly affects innovative, industrial, and mechanical applications, especially in the oil and gas industries. The corrosion conceivably influences industrial equipment; it deteriorates the environment and lessens the equipment/infrastructure's lifetime. Considering the significant impact of corrosion in our daily lives, this review article aims to briefly discuss the significance of corrosion and different control methods with special attention on corrosion inhibitors. The classification of corrosion inhibitors based on types and their advantage/limitations, and heterocyclic compounds as potential corrosion inhibitors, mainly nitrogen-based compounds (pyridine (1N), pyrimidine (2N), and triazines (3N) fused ring benzimidazole, etc.), and their biological significance has been discussed in detail. The mechanism, challenges, and applications of heterocyclic compounds as corrosion inhibitors in various industrial relevant corrosive environments such as acid pickling, descaling operation in the desalination plant, oil gas industry, etc., have also been highlighted in the review.