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1.
Hermaphroditic chirality of a D2-symmetric saddle-shaped porphyrin in multicomponent spontaneous optical resolution: inclusion cocrystals with double-helical porphyrin arrays.
Mizuno, Yukitami; Alam, Md Akhtarul; Tsuda, Akihiko; Kinbara, Kazushi; Yamaguchi, Kentaro; Aida, Takuzo.
Angew Chem Int Ed Engl ; 45(23): 3786-90, 2006 Jun 02.
Article in English | MEDLINE | ID: mdl-16671146

Subject(s)
Porphyrins/chemistry , Acetates/chemistry , Acetonitriles/chemistry , Crystallization , Mandelic Acids/chemistry , Molecular Conformation , Stereoisomerism
2.
Nonlinear amplification of circular dichroism activity upon cyclodimerization of a chiral saddle-shaped porphyrin.
Mizuno, Yukitami; Aida, Takuzo.
Chem Commun (Camb) ; (1): 20-1, 2003 Jan 07.
Article in English | MEDLINE | ID: mdl-12610945

ABSTRACT

A cyclic dimer of chiral saddle-shaped porphyrin with p-xylylene linkers, upon interaction with mandelic acid, showed an enhanced circular dichroism activity, which was more than 7 times as large as that of a monomeric reference.

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