A simple and soft chemical deaggregation method producing single-digit detonation nanodiamonds.

Detonation nanodiamonds (DNDs) are a class of very small and spherical diamond nanocrystals. They are used in polymer reinforcement materials or as drug delivery systems in the field of nanomedicine. Synthesized by detonation, only the final deaggregation step down to the single-digit nanometer size (<10 nm) unfolds their full potential. Existing deaggregation methods mainly rely on mechanical forces, such as high-power sonication or bead milling. These techniques entail drawbacks such as contamination of the sample and the need for a specialized apparatus. In this paper, we report a purely chemical deaggregation method by simply combining oxidation in air followed by a boiling acid treatment, to produce highly stable single-digit DNDs in a suspension. The resulting DNDs are surface functionalized with carboxyl groups, the final boiling acid treatment removes primary metal contaminants such as magnesium, iron or copper and the nanoparticles remain dispersed over a wide pH range. Our method can be easily carried out in a standard chemistry laboratory with commonly available laboratory apparatus. This is a key step for many DND-based applications, ranging from materials science to biological or medical applications.

Room-temperature hyperpolarization of polycrystalline samples with optically polarized triplet electrons: pentacene or nitrogen-vacancy center in diamond?

We demonstrate room-temperature 13C hyperpolarization by dynamic nuclear polarization (DNP) using optically polarized triplet electron spins in two polycrystalline systems: pentacene-doped [carboxyl-13C] benzoic acid and microdiamonds containing nitrogen-vacancy (NV-) centers. For both samples, the integrated solid effect (ISE) is used to polarize the 13C spin system in magnetic fields of 350-400 mT. In the benzoic acid sample, the 13C spin polarization is enhanced by up to 0.12 % through direct electron-to-13C polarization transfer without performing dynamic 1H polarization followed by 1H-13C cross-polarization. In addition, the ISE has been successfully applied to polarize naturally abundant 13C spins in a microdiamond sample to 0.01 %. To characterize the buildup of the 13C polarization, we discuss the efficiencies of direct polarization transfer between the electron and 13C spins as well as that of 13C-13C spin diffusion, examining various parameters which are beneficial or detrimental for successful bulk dynamic 13C polarization.

Publisher Correction: Observation of dark states in a superconductor diamond quantum hybrid system.

This corrects the article DOI: 10.1038/ncomms4524.

Manipulation of single nanodiamonds to ultrathin fiber-taper nanofibers and control of NV-spin states toward fiber-integrated λ-systems.

We report on the coupling of single nitrogen vacancy (NV) centers to ultrathin fiber-taper nanofibers by the manipulation of single diamond nanocrystals on the nanofibers under real-time observation of nanodiamond fluorescence. Spin-dependent fluorescence of the single NV centers is efficiently detected through the nanofiber. We show control of the spin sub-level structure of the electronic ground state using an external magnetic field and clearly observe a frequency fine tuning of [Formula: see text]. This observation demonstrates a possibility of realizing fiber-integrated quantum λ-systems, which can be used for various quantum information devices including push-pull quantum memory and quantum gates.

Germanium-Vacancy Single Color Centers in Diamond.

Atomic-sized fluorescent defects in diamond are widely recognized as a promising solid state platform for quantum cryptography and quantum information processing. For these applications, single photon sources with a high intensity and reproducible fabrication methods are required. In this study, we report a novel color center in diamond, composed of a germanium (Ge) and a vacancy (V) and named the GeV center, which has a sharp and strong photoluminescence band with a zero-phonon line at 602 nm at room temperature. We demonstrate this new color center works as a single photon source. Both ion implantation and chemical vapor deposition techniques enabled fabrication of GeV centers in diamond. A first-principles calculation revealed the atomic crystal structure and energy levels of the GeV center.

Improving the coherence time of a quantum system via a coupling to a short-lived system.

In this Letter, we propose a counterintuitive use of a hybrid system where the coherence time of a quantum system can be significantly improved by coupling it with a system of a shorter coherence time. Coupling a two-level system with a single nitrogen-vacancy (NV^{-}) center, a dark state of the NV^{-} center naturally forms after the hybridization. We show that this dark state becomes robust against noise due to the coupling even when the coherence time of the two-level system is much shorter than that of the NV^{-} center. Our proposal opens a new way to use a quantum hybrid system for the realization of robust quantum information processing.

Observation of dark states in a superconductor diamond quantum hybrid system.

The hybridization of distinct quantum systems has opened new avenues to exploit the best properties of these individual systems. Superconducting circuits and electron spin ensembles are one such example. Strong coupling and the coherent transfer and storage of quantum information has been achieved with nitrogen vacancy centres in diamond. Recently, we have observed a remarkably sharp resonance (~1 MHz) at 2.878 GHz in the spectrum of flux qubit negatively charged nitrogen vacancy diamond hybrid quantum system under zero external magnetic field. This width is much narrower than that of both the flux qubit and spin ensemble. Here we show that this resonance is evidence of a collective dark state in the ensemble, which is coherently driven by the superposition of clockwise and counter-clockwise macroscopic persistent supercurrents flowing in the flux qubit. The collective dark state is a unique physical system and could provide a long-lived quantum memory.

Towards realizing a quantum memory for a superconducting qubit: storage and retrieval of quantum states.

We have built a hybrid system composed of a superconducting flux qubit (the processor) and an ensemble of nitrogen-vacancy centers in diamond (the memory) that can be directly coupled to one another, and demonstrated how information can be transferred from the flux qubit to the memory, stored, and subsequently retrieved. We have established the coherence properties of the memory and succeeded in creating an entangled state between the processor and memory, demonstrating how the entangled state's coherence is preserved. Our results are a significant step towards using an electron spin ensemble as a quantum memory for superconducting qubits.

Coherent coupling of a superconducting flux qubit to an electron spin ensemble in diamond.

During the past decade, research into superconducting quantum bits (qubits) based on Josephson junctions has made rapid progress. Many foundational experiments have been performed, and superconducting qubits are now considered one of the most promising systems for quantum information processing. However, the experimentally reported coherence times are likely to be insufficient for future large-scale quantum computation. A natural solution to this problem is a dedicated engineered quantum memory based on atomic and molecular systems. The question of whether coherent quantum coupling is possible between such natural systems and a single macroscopic artificial atom has attracted considerable attention since the first demonstration of macroscopic quantum coherence in Josephson junction circuits. Here we report evidence of coherent strong coupling between a single macroscopic superconducting artificial atom (a flux qubit) and an ensemble of electron spins in the form of nitrogen-vacancy colour centres in diamond. Furthermore, we have observed coherent exchange of a single quantum of energy between a flux qubit and a macroscopic ensemble consisting of about 3 × 10(7) such colour centres. This provides a foundation for future quantum memories and hybrid devices coupling microwave and optical systems.

Ultralong spin coherence time in isotopically engineered diamond.

As quantum mechanics ventures into the world of applications and engineering, materials science faces the necessity to design matter to quantum grade purity. For such materials, quantum effects define their physical behaviour and open completely new (quantum) perspectives for applications. Carbon-based materials are particularly good examples, highlighted by the fascinating quantum properties of, for example, nanotubes or graphene. Here, we demonstrate the synthesis and application of ultrapure isotopically controlled single-crystal chemical vapour deposition (CVD) diamond with a remarkably low concentration of paramagnetic impurities. The content of nuclear spins associated with the (13)C isotope was depleted to 0.3% and the concentration of other paramagnetic defects was measured to be <10(13) cm(-3). Being placed in such a spin-free lattice, single electron spins show the longest room-temperature spin dephasing times ever observed in solid-state systems (T2=1.8 ms). This benchmark will potentially allow observation of coherent coupling between spins separated by a few tens of nanometres, making it a versatile material for room-temperature quantum information processing devices. We also show that single electron spins in the same isotopically engineered CVD diamond can be used to detect external magnetic fields with a sensitivity reaching 4 nT Hz(-1/2) and subnanometre spatial resolution.