N-doped oxidized carbon dots for methanol sensing in alcoholic beverages.

Methanol (MeOH) adulteration in alcoholic beverages resulting in irreparable health damage demands highly sensitive and cost-effective sensors for its quantification. As carbon dots are emerging as new biocompatible and sustainable light-emitting detectors, this work demonstrates the hydrothermally prepared nitrogen-doped oxidized carbon dots (NOCDs) as on-off fluorescent nanoprobes to detect MeOH traces in water and alcoholic beverages. The presence of 1% of MeOH in distilled water is found to decrease the NOCD fluorescent emission intensity by more than 90% whereas up to 70% ethanol (EtOH) content changes the signal to within 20% of its initial value. HR-TEM analysis reveals the agglomeration of the nanoprobes suspended in MeOH. Due to their selectivity towards MeOH, the fluorescent nanoprobes were successfully tested using a few MeOH spiked branded and unbranded Mexican alcoholic beverages. Varying degrees of signal quenching is observed from the fluorescent nanoprobes dispersed in different pristine beverages with a detection limit of less than 0.11 v%. Herein, we establish a new perspective towards economically viable non-toxic fluorescent probes as a potential alternative for the detection of MeOH in alcoholic beverages.

Nonresonant quadrupolar second-harmonic generation in isotropic solids by use of two orthogonally polarized laser beams.

We demonstrate an experimental technique for isolating and enhancing quadrupolar second-harmonic generation in isotropic materials by using two orthogonally polarized laser beams that create wavelength-scale, forward-radiating gradients in the second-harmonic polarization.

Single-beam and enhanced two-beam second-harmonic generation from silicon nanocrystals by use of spatially inhomogeneous femtosecond pulses.

Optical second-harmonic generation (SHG) is used as a noninvasive probe of the interfaces of Si nanocrystals (NCs) embedded uniformly in an SiO2 matrix. Measurements of the generated SH mode verify that the second-harmonic polarization has a nonlocal dipole form proportional to (E x Delta inverted) E that depends on inhomogeneities in the incident field E, as proposed in recent models based on a locally noncentrosymmetric dipolar response averaged over the spherical NC interfaces. A two-beam SHG geometry is found to enhance this polarization greatly compared to single-beam SHG, yielding strong signals useful for scanning, spectroscopy, and real-time monitoring. This configuration provides a general strategy for enhancing the second-order nonlinear response of centrosymmetric samples, as demonstrated here for both Si nanocomposites and their glass substrates.

On the apparent superluminality of evanescent waves.

There have been many recent theoretical and experimental reports on the propagation of light pulses at speeds exceeding the speed of light in vacuum $c$ within media with anomalous dispersion, either opaque or with gain. Superluminal propagation has also been reported within vacuum, in the case of inhomogeneous pulses. In this paper we show that the observations of superluminal and non-causal propagation of evanescent pulses under the conditions of frustrated internal reflection are only apparent, and that they can be simply explained employing an explicitly (sub)luminal causal theory. However, the usual one-dimensional approach to the analysis of pulse propagation has to be abandoned and the spatial extent of the incoming pulse along the directions normal to the propagation direction has to be accounted for to correctly interpret the propagation speed of these evanescent waves. We illustrate our theory with animations of the time development of a pulse built upon the Huygen's construction.