Evaluation of the Char Formation During the Hydrothermal Treatment of Wooden Balls.

With wooden balls, a visualization of the hydrothermal carbonization to show the progress of the conversion to char is presented. In the present study, the balls represent the particles of biomass to investigate the differences in conversion outside and inside of biomass particles, during hydrothermal carbonization. A special focus is on hydrochar and pyrochar formation. The wooden balls are treated in subcritical water at 220 °C for holding times between 0 and 960 min. Even after 960 min, hydrolysis of the original biomass is incomplete as cellulose and hemicellulose are linked by lignin, inhibiting the reaction with water. Moreover, two different pathways of char production can be observed. Inside of the wooden ball pyrochar is formed as any water got that deep in, on the surface hydrochar is fixed, originated from the surrounding liquid. On the ground of the HTC reactor, a thin, brittle precipitate of likely hydrochar or humins can be found either from the precipitation of loosely attached compounds on the surface of the biomass or direct precipitation from the liquid.

Activated Carbon from Palm Date Seeds for CO2 Capture.

The process of carbon dioxide capture and storage is seen as a critical strategy to mitigate the so-called greenhouse effect and the planetary climate changes associated with it. In this study, we investigated the CO2 adsorption capacity of various microporous carbon materials originating from palm date seeds (PDS) using green chemistry synthesis. The PDS was used as a precursor for the hydrochar and activated carbon (AC). Typically, by using the hydrothermal carbonization (HTC) process, we obtained a powder that was then subjected to an activation step using KOH, H3PO4 or CO2, thereby producing the activated HTC-PDS samples. Beyond their morphological and textural characteristics, we investigated the chemical composition and lattice ordering. Most PDS-derived powders have a high surface area (>1000 m2 g-1) and large micropore volume (>0.5 cm3 g-1). However, the defining characteristic for the maximal CO2 uptake (5.44 mmol g-1, by one of the alkaline activated samples) was the lattice restructuring that occurred. This work highlights the need to conduct structural and elemental analysis of carbon powders used as gas adsorbents and activated with chemicals that can produce graphite intercalation compounds.

Influence of Reaction Conditions on Hydrothermal Carbonization of Fructose.

Hydrothermal carbonization is a powerful way to convert cellulosic waste into valuable platform chemicals and carbonaceous materials. In this study, to optimize the process, fructose was chosen as the carbon precursor and the influence of reaction time, acid catalysis, feed gas and pressure on the conversion products is evaluated. 5-hydroxymethylfurfural (HMF) is produced in high amounts in relatively short time. Both strong and weak acids accelerate fructose conversion. Levulinic acid (LevA) formation is faster than that of hydrothermal (HT) carbon in acidic conditions. Strong acid catalysts should be considered to target preferentially LevA production, whereas milder conditions should be preferred for HMF production. Moreover, a slight initial overpressure of the reactor is always beneficial in terms of conversion. FT-IR and 13 C ss-NMR spectroscopy and SEM showed that HT carbon evolves through time from a furanic-based structure with alkylic linkers to an increasingly cross-linked condensed structure. MALDI-ToF mass spectrometry showed the existence of a series of oligomers in a mass range within 650 Da and 1500 Da formed by condensation of repeating units.

Hydrothermal Conversion of Spent Sugar Beets into High-Value Platform Molecules.

The growing importance of bio-based products, combined with the desire to decrease the production of wastes, boosts the necessity to use wastes as raw materials for bio-based products. A waste material with a large potential is spent sugar beets, which are mainly used as animal feeds or fertilizers. After hydrothermal treatment, the produced chars exhibited an H/C ratio of 1.2 and a higher heating value of 22.7 MJ/kg, which were similar to that of subbituminous coal and higher than that of lignite. Moreover, the treatment of 25 g/L of glucose and 22 g/L of fructose by heating up to 160 °C led to a possible application of spent sugar beets for the production of 5-hydroxymethylfurfural. In the present study, the maximum concentration of 5-hydroxymethylfurfural was 3.4 g/L after heating up to 200 °C.