ABSTRACT
This review discusses the development and application of nanocellulose (NC)-aerogels, a sustainable and biodegradable biomaterial, with enhanced flame retardant (FR) properties. NC-aerogels combine the excellent physical and mechanical properties of NC with the low density and thermal conductivity of aerogels, making them promising for thermal insulation and other fields. However, the flammability of NC-aerogels limits their use in some applications, such as electromagnetic interference shielding, oil/water separation, and flame-resistant textiles. The review covers the design, fabrication, modification, and working mechanism of NC porous materials, focusing on how advanced technologies can impart FR properties into them. The review also evaluates the FR performance of NC-aerogels by employing widely recognized tests, such as the limited oxygen index, cone calorimeter, and UL-94. The review also explores the integration of innovative and eco-friendly materials, such as MXene, metal-organic frameworks, dopamine, lignin, and alginate, into NC-aerogels, to improve their FR performance and functionality. The review concludes by outlining the potential, challenges, and limitations of future research on FR NC-aerogels, identifying the obstacles and potential solutions, and understanding the current progress and gaps in the field.
ABSTRACT
Solid waste management of the potato peels, generated during the processing of potatoes, can be done sustainably by adding value to the peel waste. Peels contains polyphenols, which serve as a defense mechanism against foreign pathogens in plants and have a variety of pharmacological properties such as antioxidant and anti-carcinogenic properties. However, specific segregation of any one polyphenol from waste can be challenging due to its complex matrix and low concentration of the targeted polyphenol. This work presents a way to combat this challenge through molecularly imprinted solid-phase extraction (MISPE) using customized graphene oxide-based molecularly imprinted composite (GOMIP) as sorbent for the selective recovery of p-hydroxy benzoic acid (P-HA) (antioxidant used in food industries), from potato peels for the effective valorization of peels. Various parameters such as flow rate, vacuum manifold pressure, conditioning solvent, washing solvent, and elution solvent were optimized for effective segregation of targeted P-HA. The imprinting factor of 2.14, obtained using breakthrough curves for GOMIP and control (graphene oxide based non-imprinted composite-GONIP) sorbent under optimized condition, indicated the ability of the sorbent GOMIP to recover P-HA from the extract of potato peels. Reusability and selectivity studies were performed for GOMIP sorbent using the real sample [potato peels extract (PPE)]. 77.44% recovery for P-HA was exhibited by the GOMIP sorbent in the MISPE cartridge as determined using HPLC. MISPE with customized GOMIP sorbent can be a sustainable approach to valorize the potato peel solid waste.
