Optimization of stabilized anaerobic landfill leachate treatment using ozonation with metallic compound using response surface methodology.

Malaysia encounters a consistent rise in the generation of solid waste and leachate on a daily basis. It should also be noted that leachate has a low degree of biodegradability (BOD5 /chemical oxygen demand [COD]), as shown by its BOD5 /COD ratio. Its high toxicity levels significantly threaten the environment, water bodies, and human well-being. High concentrations of COD, color, and ammoniacal nitrogen (NH3 -N) in leachate prevent this wastewater from being allowed to be discharged directly into the water body. Therefore, an effective process to remove the pollutant is desired. The aims of this study are to investigate the performance of ozonation with two metallic compounds, ZrCl4 and SnCl4 , and optimize their performance using response surface methodology (RSM). In this study, the performance of ozonation with ZrCl4 (O3 /ZrCl4 ) recorded better pollutant removals compared with the ozonation with tin tetrachloride (O3 /SnCl4 ), as seen in the removals of 99.8%, 93.5%, and 46.3% for color, COD, and NH3 -N, respectively. These removals were achieved by following the experimental model (optimum experiment condition) generated by RSM at O3 dosage of 31 g/m3 , COD and ZrCl4 dosage ratio (COD, mg/L/ZrCl4 , mg/L) of 1:1.35, with the pH solution of 8.78 and reaction time of 89 min. The R2 of each parameter for this model was recorded as 0.999 (COD), 0.999 (color), and 0.998 (NH3 -N), respectively. These data indicated that the model is well fitted as the predicted data by statistical calculation and in good agreement with the actual data. PRACTITIONER POINTS: The performance of O3 /ZrCl4 and O3 /SnCl4 was examined for remediate stabilized landfill leachate. The performance of O3 /ZrCl4 and O3 /SnCl4 was optimized using RSM, and a set of experimental models was generated and tested. O3 /ZrCl4 recorded the higher removal of COD, color, and NH3 -N compared with O3 /SnCl4 . At best condition, both methods recorded removal as 89% to 99.8% of pollutants in leachate and product clear effluent. This finding gives a new approach to treat landfill leachate effectively and efficiently.

Aperiodic differential method associated with FFF: an efficient electromagnetic computational tool for integrated optical waveguides modelization.

A reformulation of the differential theory associated with fast Fourier factorization used for periodic diffractive structures is presented. The incorporation of a complex coordinate transformation in the propagation equations allows the modeling of semi-infinite open problems through an artificially periodized space. Hence, the outgoing wave conditions of an open structure must be satisfied. On the other hand, the excitation technique must be adjusted to adapt with guided structures. These modifications turn the differential theory into an aperiodic tool used with guided optical structure. Our method is verified through numerical results and comparisons with the aperiodic Fourier modal method showing enhanced convergence and accuracy, especially when complex-shaped photonic guided devices are considered.

Optimization of all-dielectric structures for color generation.

In this work, we propose an inversion scheme to tailor the chromatic response of an all-dielectric structure. To this end, we couple, through a previously defined objective functional involving the concept of color difference, a forward solver with an optimization algorithm. The former is based on the differential method, whereas the latter is based on particle swarm optimization. The optimal geometrical parameters of the structure that generates a specific color are obtained through the solution of an approximation problem. We illustrate the performance of our inversion scheme through examples and discuss its limitations and potential applications.